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A Novel Allyl Transfer Coupled with a Grob Fragmentation
Alternative Title一个与Grob碎裂相偶联的新颖烯丙基重排反应
Li SG(李绍刚); Chen HJ(陈慧君); Yang YY(杨洋洋); Wu WJ(武文菊); Wu YK(伍贻康)
Source PublicationChem.-Asian J.
AbstractA novel acid-promoted rearrangement is disclosed. In the previously unknown transformation, an allyl group migrated to an in situ formed carbocation stabilized by an electron-rich aryl or heteroaryl group, resulting in a stereoselective intramolecular Grob fragmentation. The outcome of the rearrangement observed with an array of substrates can be satisfactorily rationalized using a working hypothesis with the aid of a six-membered transition state similar to those proposed for the anionic oxy-Cope or oxonia-Cope rearrangements, but involving only one instead of two double bonds.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000363472800003
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Document Type期刊论文
Corresponding AuthorWu YK(伍贻康)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Li SG,Chen HJ,Yang YY,et al. A Novel Allyl Transfer Coupled with a Grob Fragmentation[J]. Chem.-Asian J.,2015,10(11):2333-2336.
APA 李绍刚,陈慧君,杨洋洋,武文菊,&伍贻康.(2015).A Novel Allyl Transfer Coupled with a Grob Fragmentation.Chem.-Asian J.,10(11),2333-2336.
MLA 李绍刚,et al."A Novel Allyl Transfer Coupled with a Grob Fragmentation".Chem.-Asian J. 10.11(2015):2333-2336.
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