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CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines
Alternative Title碘化亚铜/草酸二酰胺配体催化的芳基(杂芳基)氯代物与胺的偶联
Zhou W(周伟)1; Fan MY(樊梦阳)1; Yin JL(殷俊力)1; Jiang YW(蒋咏文)1; Ma DW(马大为)1
Source PublicationJ. Am. Chem. Soc.
AbstractA class of oxalic diamides are found to be effective ligands for promoting CuI-catalyzed aryl amination with less reactive (hetero)aryl chlorides. The reaction proceeds at 120 degrees C with K3PO4 as the base in DMSO to afford a wide range of (hetero)aryl amines in good to excellent yields. The bis(N-aryl) substituted oxalamides are superior ligands to N-aryl-N'-alkyl substituted or bis(N-alkyl) substituted oxalamides. Both the electronic nature and the steric property of the aromatic rings in ligands are important for their efficiency.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000361930000023
Citation statistics
Cited Times:73[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorMa DW(马大为)
Affiliation1.中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhou W,Fan MY,Yin JL,et al. CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines[J]. J. Am. Chem. Soc.,2015,137(37):11942-11945.
APA 周伟,樊梦阳,殷俊力,蒋咏文,&马大为.(2015).CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines.J. Am. Chem. Soc.,137(37),11942-11945.
MLA 周伟,et al."CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines".J. Am. Chem. Soc. 137.37(2015):11942-11945.
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