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学科主题: 生命有机化学
题名: O-Glycosylation methods in the total synthesis of complex natural glycosides
其他题名: 氧-糖苷化在天然糖苷类化合物合成中的应用
作者: Yang Y(杨友)1; Zhang XH(张夏衡)1; Yu B(俞飚)1
通讯作者: 杨友 ; 俞飚
刊名: Nat. Prod. Rep.
发表日期: 2015
DOI: 10.1039/c5np00033e
卷: 32, 期:9, 页:1331-1355
收录类别: SCI
文章类型: 论文
英文摘要: The total syntheses of 33 complex natural O-glycosides, such as the glycosides of macrocyclic lactones/lactams, enediynes, angucyclines, and anthracyclines, are highlighted, with a major focus being placed on the O-glycosylation reactions which connect the saccharides and the aglycones. These successful O-glycosylation reactions employ such donors as glycosyl bromides, fluorides, iodides, trichloroacetimidates, N-phenyl trifluoroacetimidates, thioglycosides, sulfoxides, heteroaryl thioglycosides, 1-hydroxyl sugars, 1-O-acetates, and ortho-alkynylbenzoates. Each synthesis is depicted starting from the O-glycosylation of the aglycone (or its precursor); the glycosylation conditions and outcomes (yields and stereoselectivities) are discussed, and the subsequent transformations toward the final target, including the elongation of the glycan, the elaboration of the aglycone, and the protecting group manipulations are also given in detail.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000360115000004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39523
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Yang Y,Zhang XH,Yu B. O-Glycosylation methods in the total synthesis of complex natural glycosides[J]. Nat. Prod. Rep.,2015,32(9):1331-1355.
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