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Conversion of Dihydroartemisinic Acid into Dihydro-epi-deoxyarteannuin B
Alternative Title将二氢青蒿酸转化为二氢-异-脱氧青蒿素B
Chen HJ(陈慧君); Hao HD(郝宏东); Wu YK(伍贻康)
Source PublicationEur. J. Org. Chem.
AbstractA facile and high-yielding one-step conversion of dihydroartemisinic acid into dihydro-epi-deoxyarteannuin B, a natural product and a pivotal compound in the synthesis of several other natural products isolated from Artemisia annua L., was developed after the systematic examination of several potentially applicable conditions. The transformation, most satisfactorily effected with Pd(OAc)(2)/CuCl2/MnO2, makes it possible to access many known potent antimalarial trioxanes from readily available artemisinic acid. Some interesting cases of differentiation between the carbonyl groups are also presented.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000358085100020
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Document Type期刊论文
Corresponding AuthorWu YK(伍贻康)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Chen HJ,Hao HD,Wu YK. Conversion of Dihydroartemisinic Acid into Dihydro-epi-deoxyarteannuin B[J]. Eur. J. Org. Chem.,2015(20):4423-4427.
APA 陈慧君,郝宏东,&伍贻康.(2015).Conversion of Dihydroartemisinic Acid into Dihydro-epi-deoxyarteannuin B.Eur. J. Org. Chem.(20),4423-4427.
MLA 陈慧君,et al."Conversion of Dihydroartemisinic Acid into Dihydro-epi-deoxyarteannuin B".Eur. J. Org. Chem. .20(2015):4423-4427.
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