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学科主题: 生命有机化学
题名: Asymmetric Total Synthesis of Mycoleptodiscin A
其他题名: Asymmetric Total Synthesis of Mycoleptodiscin A
作者: Zhou SP(周述鹏); Chen H(陈浩); Luo YJ(罗乙杰); Zhang WH(张纹豪); Li A(李昂)
通讯作者: 李昂
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201501021
卷: 54, 期:23, 页:6878-6882
收录类别: SCI
文章类型: 论文
英文摘要: The first total synthesis of mycoleptodiscinA, a structurally unusual indolosesquiterpenoid possessing an ortho-benzoquinone motif, has been accomplished. A sulfone alkylation coupled two readily available fragments to give an aryl triene intermediate. The tetracyclic core of the molecule was assembled through a highly enantioselective iridium-catalyzed polyene cyclization. The benzylic homologation was achieved by a cationic cyanation. The indole motif was constructed via a copper-mediated intramolecular CN bond formation at a late stage.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000355314100036
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39505
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Zhou SP,Chen H,Luo YJ,et al. Asymmetric Total Synthesis of Mycoleptodiscin A[J]. Angew. Chem.-Int. Edit.,2015,54(23):6878-6882.
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