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学科主题: 生命有机化学
题名: Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation
其他题名: 非Nod因子依赖的固氮相关的肌醇并环单糖bradyrhizose的合成
作者: Li W(李微)1; SILIPO ALBA1; MOLINARO ANTONIO1; Yu B(俞飚)1
通讯作者: MOLINARO ANTONIO ; 俞飚
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c5cc00752f
卷: 51, 期:32, 页:6964-6967
收录类别: SCI
文章类型: 论文
英文摘要: The symbiosis of Bradyrhizobium sp. BTAi1 with its host plant Aeschynomene indica relies on a Nod-factor independent mechanism, wherein the Bradyrhizobium O-antigen is regarded as a key factor. This O-antigen polysaccharide is composed of a unique C10 monosaccharide, namely bradyrhizose, which has a galactose-inositol trans-fused scaffold, via a homogeneous alpha-(1 -> 7)-linkage. Herein, we report the first synthesis of bradyrhizose. The scalable synthesis requires 26 steps in a high overall yield of 9%, with the inositol scaffold being constructed effectively via a Ferrier II rearrangement from a fully functionalized C2 and C4 branched pyranose derivative.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000352630600018
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39500
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 生命有机化学国家重点实验室
2.意大利那不勒斯费德里克二世大学

Recommended Citation:
Li W,SILIPO ALBA,MOLINARO ANTONIO,et al. Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation[J]. Chem. Commun.,2015,51(32):6964-6967.
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