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Total Synthesis of Leucosceptroids A and B
Alternative TitleLeucosceptroids A and B的全合成
Guo S(郭盛); Liu J(刘杰); Ma DW(马大为)
Source PublicationAngew. Chem.-Int. Edit.
AbstractLeucosceptroidsA and B are sesterterpenoids with potent antifeedant and antifungal activities. A more efficient gram-scale total synthesis of leucosceptroidB and the first total synthesis of leucosceptroidA are presented. The key transformations include an aldol reaction between a substituted dihydrofuranone and an (S)-citronellal-derived aldehyde, a SmI2-mediated intramolecular ketyl-olefin radical cyclization, and final-stage alcohol oxidation.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000348372900043
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Document Type期刊论文
Corresponding AuthorMa DW(马大为)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Guo S,Liu J,Ma DW. Total Synthesis of Leucosceptroids A and B[J]. Angew. Chem.-Int. Edit.,2015,54(4):1298-1301.
APA 郭盛,刘杰,&马大为.(2015).Total Synthesis of Leucosceptroids A and B.Angew. Chem.-Int. Edit.,54(4),1298-1301.
MLA 郭盛,et al."Total Synthesis of Leucosceptroids A and B".Angew. Chem.-Int. Edit. 54.4(2015):1298-1301.
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