| Total Synthesis of Leucosceptroids A and B | |
| Alternative Title | Leucosceptroids A and B的全合成 |
| Guo S(郭盛); Liu J(刘杰); Ma DW(马大为) | |
| 2015 | |
| Source Publication | Angew. Chem.-Int. Edit.
 |
| Volume | 54Issue:4Pages:1298-1301 |
| Abstract | LeucosceptroidsA and B are sesterterpenoids with potent antifeedant and antifungal activities. A more efficient gram-scale total synthesis of leucosceptroidB and the first total synthesis of leucosceptroidA are presented. The key transformations include an aldol reaction between a substituted dihydrofuranone and an (S)-citronellal-derived aldehyde, a SmI2-mediated intramolecular ketyl-olefin radical cyclization, and final-stage alcohol oxidation. |
| Subtype | 论文 |
| Subject Area | 生命有机化学 |
| DOI | 10.1002/anie.201410134 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000348372900043 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39486 |
| Collection | 生命有机化学国家重点实验室 |
| Corresponding Author | Ma DW(马大为) |
| Affiliation | 中科院上海有机化学研究所, 生命有机化学国家重点实验室 |
| Recommended Citation GB/T 7714 | Guo S,Liu J,Ma DW. Total Synthesis of Leucosceptroids A and B[J]. Angew. Chem.-Int. Edit.,2015,54(4):1298-1301. |
| APA | 郭盛,刘杰,&马大为.(2015).Total Synthesis of Leucosceptroids A and B.Angew. Chem.-Int. Edit.,54(4),1298-1301. |
| MLA | 郭盛,et al."Total Synthesis of Leucosceptroids A and B".Angew. Chem.-Int. Edit. 54.4(2015):1298-1301. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015074.pdf（557KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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