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学科主题: 生命有机化学
题名: Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B
其他题名: Melanoxadin, MR-93A, Melanoxazal和MR-93B的绝对构型
作者: He TJ(何天骏)1; Zhu SJ(朱时俊)1; Lu XW(陆晓伟)1; Wu YK(伍贻康)1; Li Y(李焰)1
通讯作者: 伍贻康 ; 李焰
刊名: Eur. J. Org. Chem.
发表日期: 2015
DOI: 10.1002/ejoc.201403287
期: 3, 页:647-654
收录类别: SCI
文章类型: 论文
英文摘要: Fungal metabolites melanoxadin, MR-93A, melanoxazal, and MR-93B were synthesized with the key stereogenic centers derived from commercially available chiral building blocks. The optically active synthetic products with well-defined absolute configurations provided authentic samples for the stereoisomers of these oxazole-containing natural products and thus allowed for unambiguous assignments of their relative and absolute configurations. The large discrepancies in the optical rotations between the natural and the pure synthetic samples are discussed. Some errors in the previously reported NMR signal assignments are also corrected.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000348436000025
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39480
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 1.湖北大学
2.中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
He TJ,Zhu SJ,Lu XW,et al. Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B[J]. Eur. J. Org. Chem.,2015(3):647-654.
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