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Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B
Alternative TitleMelanoxadin, MR-93A, Melanoxazal和MR-93B的绝对构型
He TJ(何天骏)1; Zhu SJ(朱时俊)1; Lu XW(陆晓伟)1; Wu YK(伍贻康)1; Li Y(李焰)1
Source PublicationEur. J. Org. Chem.
AbstractFungal metabolites melanoxadin, MR-93A, melanoxazal, and MR-93B were synthesized with the key stereogenic centers derived from commercially available chiral building blocks. The optically active synthetic products with well-defined absolute configurations provided authentic samples for the stereoisomers of these oxazole-containing natural products and thus allowed for unambiguous assignments of their relative and absolute configurations. The large discrepancies in the optical rotations between the natural and the pure synthetic samples are discussed. Some errors in the previously reported NMR signal assignments are also corrected.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000348436000025
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Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWu YK(伍贻康); Li Y(李焰)
2.中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
He TJ,Zhu SJ,Lu XW,et al. Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B[J]. Eur. J. Org. Chem.,2015(3):647-654.
APA 何天骏,朱时俊,陆晓伟,伍贻康,&李焰.(2015).Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B.Eur. J. Org. Chem.(3),647-654.
MLA 何天骏,et al."Absolute Configurations of Melanoxadin, MR-93A, Melanoxazal, and MR-93B".Eur. J. Org. Chem. .3(2015):647-654.
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