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Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis
Alternative Title高价碘试剂通过可见光催化实现化学选择的脱硼脱羧烯基化反应
Huang HC(黄汉初); Jia KF(贾坤方); Chen YY(陈以昀)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:6Pages:1881-1884
AbstractChemoselective C(sp3)C(sp2) coupling reactions under mild reaction conditions are useful for synthesizing alkyl-substituted alkenes having sensitive functional groups. Reported here is a visible-light-induced chemoselective alkenylation through a deboronation/decarboxylation sequence under neutral aqueous reaction conditions at room temperature. This reaction represents the first hypervalent-iodineenabled radical decarboxylative alkenylation reaction, and a novel benziodoxole-vinyl carboxylic acid reaction intermediate was isolated. This C(sp3)C(sp2) coupling reaction leads to aryl-and acyl-substituted alkenes containing various sensitive functional groups. The excellent chemoselectivity, stable reactants, and neutral aqueous reaction conditions of the reaction suggest future biomolecule applications.
Subtype论文
Subject Area生命有机化学
DOI10.1002/anie.201410176
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000349209200037
Citation statistics
Cited Times:90[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39476
Collection生命有机化学国家重点实验室
Corresponding AuthorChen YY(陈以昀)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Huang HC,Jia KF,Chen YY. Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis[J]. Angew. Chem.-Int. Edit.,2015,54(6):1881-1884.
APA 黄汉初,贾坤方,&陈以昀.(2015).Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis.Angew. Chem.-Int. Edit.,54(6),1881-1884.
MLA 黄汉初,et al."Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis".Angew. Chem.-Int. Edit. 54.6(2015):1881-1884.
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