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Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights
Alternative Title丙二醛的氧化重排: 底物范围与机理
Yu X(于欣)1; Liu Z(刘政)1; Xia ZL(夏自磊)1; Shen ZG(申志高)1; Pan XX(潘希险)1; Zhang H(张慧)1; Xie WQ(谢卫青)1
2014
Source PublicationRSC Adv.
Volume4Issue:96Pages:53397-53401
AbstractA novel oxidative rearrangement of malondialdehyde was described. Under the effect of H2O2, malondialdehyde smoothly transferred to carboxylic acid with C-C bond cleavage in good to excellent yields. Mechanistic studies showed that this reaction proceeded via the formation of a 1,2-dioxolane intermediate, followed by concert C-C, O-O, C-H bond cleavage and a hydride shift.
Subject Area有机化学
DOI10.1039/c4ra11237g
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39173
Collection上海有机化学研究所
Corresponding AuthorZhang H(张慧); Xie WQ(谢卫青)
Affiliation1.上海大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yu X,Liu Z,Xia ZL,et al. Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights[J]. RSC Adv.,2014,4(96):53397-53401.
APA 于欣.,刘政.,夏自磊.,申志高.,潘希险.,...&谢卫青.(2014).Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights.RSC Adv.,4(96),53397-53401.
MLA 于欣,et al."Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights".RSC Adv. 4.96(2014):53397-53401.
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