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学科主题: 有机化学
题名: Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights
其他题名: 丙二醛的氧化重排: 底物范围与机理
作者: Yu X(于欣)1; Liu Z(刘政)1; Xia ZL(夏自磊)1; Shen ZG(申志高)1; Pan XX(潘希险)1; Zhang H(张慧)1; Xie WQ(谢卫青)1
通讯作者: 张慧 ; 谢卫青
刊名: RSC Adv.
发表日期: 2014
DOI: 10.1039/c4ra11237g
卷: 4, 期:96, 页:53397-53401
收录类别: SCI
英文摘要: A novel oxidative rearrangement of malondialdehyde was described. Under the effect of H2O2, malondialdehyde smoothly transferred to carboxylic acid with C-C bond cleavage in good to excellent yields. Mechanistic studies showed that this reaction proceeded via the formation of a 1,2-dioxolane intermediate, followed by concert C-C, O-O, C-H bond cleavage and a hydride shift.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39173
Appears in Collections:上海有机化学研究所_期刊论文

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作者单位: 1.上海大学
2.中科院上海有机化学研究所

Recommended Citation:
Yu X,Liu Z,Xia ZL,et al. Oxidative rearrangement of malondialdehyde: substrate scope and mechanistic insights[J]. RSC Adv.,2014,4(96):53397-53401.
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