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Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions
Alternative Title丙炔酸与N-杂环在无过渡金属条件下的脱羧羟胺化反应
Pan XX(潘希险)1; Wan XL(万晓龙)1; Yu X(于欣)1; Zhang H(张慧)1; Xie WQ(谢卫青)1
2014
Source PublicationSynthesis
Volume46Issue:15Pages:2057-2064
AbstractA decarboxylative hydroamination cascade reaction of 3-arylpropiolic acids with N-heterocycles under transition-metal-free conditions was developed. 3-Arylpropiolic acids were found to react smoothly with a range of N-heterocycles under the effect of t-BuOK to afford N-vinyl heterocycles in moderate to excellent yields. This reaction represents the first decarboxylative hydroamination of 3-arylpropiolic acids without the aid of a transition-metal catalyst.
Subject Area有机化学
DOI10.1055/s-0033-1338622
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39170
Collection上海有机化学研究所
Corresponding AuthorZhang H(张慧); Xie WQ(谢卫青)
Affiliation1.上海大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Pan XX,Wan XL,Yu X,et al. Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions[J]. Synthesis,2014,46(15):2057-2064.
APA 潘希险,万晓龙,于欣,张慧,&谢卫青.(2014).Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions.Synthesis,46(15),2057-2064.
MLA 潘希险,et al."Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions".Synthesis 46.15(2014):2057-2064.
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