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学科主题: 有机化学
题名: Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions
其他题名: 丙炔酸与N-杂环在无过渡金属条件下的脱羧羟胺化反应
作者: Pan XX(潘希险)1; Wan XL(万晓龙)1; Yu X(于欣)1; Zhang H(张慧)1; Xie WQ(谢卫青)1
通讯作者: 张慧 ; 谢卫青
刊名: Synthesis
发表日期: 2014
DOI: 10.1055/s-0033-1338622
卷: 46, 期:15, 页:2057-2064
收录类别: SCI
英文摘要: A decarboxylative hydroamination cascade reaction of 3-arylpropiolic acids with N-heterocycles under transition-metal-free conditions was developed. 3-Arylpropiolic acids were found to react smoothly with a range of N-heterocycles under the effect of t-BuOK to afford N-vinyl heterocycles in moderate to excellent yields. This reaction represents the first decarboxylative hydroamination of 3-arylpropiolic acids without the aid of a transition-metal catalyst.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39170
Appears in Collections:上海有机化学研究所_期刊论文

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作者单位: 1.上海大学
2.中科院上海有机化学研究所

Recommended Citation:
Pan XX,Wan XL,Yu X,et al. Decarboxylative Hydroamination of 3-Arylpropiolic Acids with N-Heterocycles under Transition-Metal-Free Conditions[J]. Synthesis,2014,46(15):2057-2064.
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