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Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex
Alternative Title色醇的不对称溴环化反应: DABCO-衍生的溴复合物的意外加速效应
Liu H(刘欢)1; Jiang GD(姜广德)1; Pan XX(潘希险)1; Wan XL(万晓龙)1; Lai YS(赖宜生)1; Ma DW(马大为)1; Xie WQ(谢卫青)1
2014
Source PublicationOrg. Lett.
Volume16Issue:7Pages:1908-1911
AbstractHighly asymmetric bromocyclization of tryptophol by using chiral anionic phase-transfer catalyst and DABCO-derived brominating reagent is described. Optimization of the reaction conditions revealed that the reaction rate was accelerated together with improvement of enantioselectivity by addition of catalytic DABCO-derived brominating reagent. From tryptophol, 3-bromofuroindoline could be directly obtained in excellent enantioselectivities by employing this novel methodology.
Subject Area有机化学
DOI10.1021/ol5004109
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39158
Collection上海有机化学研究所
Corresponding AuthorLai YS(赖宜生); Ma DW(马大为); Xie WQ(谢卫青)
Affiliation1.中国药科大学
2.上海大学
3.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Liu H,Jiang GD,Pan XX,et al. Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex[J]. Org. Lett.,2014,16(7):1908-1911.
APA 刘欢.,姜广德.,潘希险.,万晓龙.,赖宜生.,...&谢卫青.(2014).Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex.Org. Lett.,16(7),1908-1911.
MLA 刘欢,et al."Highly Asymmetric Bromocyclization of Tryptophol: Unexpected Accelerating Effect of DABCO-Derived Bromine Complex".Org. Lett. 16.7(2014):1908-1911.
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