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学科主题: 物理有机化学
题名: Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts
其他题名: 通过杂原子迈克尔-迈克尔加成反应合成螺[苯并二氢吡喃/四氢噻酚3,3'-氧化吲哚]构架: 双官能催化剂控制对映选择性
作者: Huang YM(黄有铭); Zheng CW(郑昌武); Chai Z(柴卓); Zhao G(赵刚)
通讯作者: 赵刚
刊名: Adv. Synth. Catal.
发表日期: 2014
DOI: 10.1002/adsc.201300833
卷: 356, 期:2-3, 页:579-583
收录类别: SCI
英文摘要: An efficient method for the construction of chiral spirooxindole-chroman and spirooxindole-tetrahydrothiophene scaffolds with three consecutive chiral centers including an all-carbon quaternary spirocenter has been developed. This method features an asymmetric thia/oxa-Michael-Michael cascade sequence in a single operation in the presence of chiral tertiary amine-thioureas as the catalysts, providing the desired products in good chemical yields and optical purities.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39156
Appears in Collections:上海有机化学研究所_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Huang YM,Zheng CW,Chai Z,et al. Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts[J]. Adv. Synth. Catal.,2014,356(2-3):579-583.
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