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Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts
Alternative Title通过杂原子迈克尔-迈克尔加成反应合成螺[苯并二氢吡喃/四氢噻酚3,3'-氧化吲哚]构架: 双官能催化剂控制对映选择性
Huang YM(黄有铭); Zheng CW(郑昌武); Chai Z(柴卓); Zhao G(赵刚)
2014
Source PublicationAdv. Synth. Catal.
Volume356Issue:2-3Pages:579-583
AbstractAn efficient method for the construction of chiral spirooxindole-chroman and spirooxindole-tetrahydrothiophene scaffolds with three consecutive chiral centers including an all-carbon quaternary spirocenter has been developed. This method features an asymmetric thia/oxa-Michael-Michael cascade sequence in a single operation in the presence of chiral tertiary amine-thioureas as the catalysts, providing the desired products in good chemical yields and optical purities.
Subject Area物理有机化学
DOI10.1002/adsc.201300833
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39156
Collection上海有机化学研究所
Corresponding AuthorZhao G(赵刚)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Huang YM,Zheng CW,Chai Z,et al. Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts[J]. Adv. Synth. Catal.,2014,356(2-3):579-583.
APA 黄有铭,郑昌武,柴卓,&赵刚.(2014).Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts.Adv. Synth. Catal.,356(2-3),579-583.
MLA 黄有铭,et al."Synthesis of Spiro[chroman/tetrahydrothiophene-3,3 '-oxindole] Scaffolds via Heteroatom-Michael-Michael Reactions: Easily Controlled Enantioselectivity via Bifunctional Catalysts".Adv. Synth. Catal. 356.2-3(2014):579-583.
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