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学科主题: 有机化学
题名: Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution
其他题名: 无过渡金属、室温下非活化烯烃在水相中的叠氮氟代
作者: Li ZD(李兆栋); Zhang CW(张成伟); Zhu L(朱林); Liu C(刘超); Li CZ(李超忠)
通讯作者: 李超忠
刊名: Org. Chem. Front.
发表日期: 2014
DOI: 10.1039/c3qo00037k
卷: 1, 页:100-104
英文摘要: We report herein the transition-metal-free azidofluorination of unactivated alkenes. Thus, the condensation of various alkenes with TMSN3 and Selectfluor in aqueous CH3CN at RT led to the efficient and regioselective synthesis of β-fluorinated alkyl azides with excellent functional group compatibility and good stereoselectivity. A single electron transfer mechanism involving the oxidative generation of azidyl radicals is proposed.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39151
Appears in Collections:上海有机化学研究所_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Li ZD,Zhang CW,Zhu L,et al. Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution[J]. Org. Chem. Front.,2014,1:100-104.
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