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Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution
Alternative Title无过渡金属、室温下非活化烯烃在水相中的叠氮氟代
Li ZD(李兆栋); Zhang CW(张成伟); Zhu L(朱林); Liu C(刘超); Li CZ(李超忠)
2014
Source PublicationOrg. Chem. Front.
Volume1Pages:100-104
AbstractWe report herein the transition-metal-free azidofluorination of unactivated alkenes. Thus, the condensation of various alkenes with TMSN3 and Selectfluor in aqueous CH3CN at RT led to the efficient and regioselective synthesis of β-fluorinated alkyl azides with excellent functional group compatibility and good stereoselectivity. A single electron transfer mechanism involving the oxidative generation of azidyl radicals is proposed.
Subject Area有机化学
DOI10.1039/c3qo00037k
URL查看原文
Language英语
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Cited Times:55[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39151
Collection上海有机化学研究所
Corresponding AuthorLi CZ(李超忠)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Li ZD,Zhang CW,Zhu L,et al. Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution[J]. Org. Chem. Front.,2014,1:100-104.
APA 李兆栋,张成伟,朱林,刘超,&李超忠.(2014).Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution.Org. Chem. Front.,1,100-104.
MLA 李兆栋,et al."Transition-Metal-Free, Room-Temperature Radical Azidofluorination of Unactivated Alkenes in Aqueous Solution".Org. Chem. Front. 1(2014):100-104.
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