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学科主题: 物理有机化学
题名: DABCO catalyzed cross-Rauhut Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight
其他题名: DABCO催化活泼烯烃与丙烯酸酯交叉Rauhut Currier酯交换反应: 底物范围与机理研究
作者: Liu W(刘文)1; Zhao G(赵刚)1
通讯作者: 赵刚
刊名: Org. Biomol. Chem.
发表日期: 2014
DOI: 10.1039/c3ob41763h
卷: 12, 期:5, 页:832-835
收录类别: SCI
英文摘要: DABCO catalyzed the cross-Rauhut-Currier/transesterification reaction of alpha-cyano-alpha,beta-unsaturated ketones and aryl acrylates was discovered. The reaction rate law was determined by an integral method under pseudo-first-order reaction conditions, which assisted in proposing the mechanism of cross-Rauhut-Currier reaction promoted by Bronsted acid and establishing the rate-determining step.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39149
Appears in Collections:上海有机化学研究所_期刊论文

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作者单位: 1.中国科技大学
2.中科院上海有机化学研究所

Recommended Citation:
Liu W,Zhao G. DABCO catalyzed cross-Rauhut Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight[J]. Org. Biomol. Chem.,2014,12(5):832-835.
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