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学科主题: 物理有机化学
题名: Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water
其他题名: 全刚性棒-棒型两亲分子: 合成、晶体结构以及水相中的自组装性质
作者: Lin F(林沨); Zhou TY(周天佑); Zhan TG(占田广); Zhao X(赵新)
通讯作者: 赵新
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.02.029
卷: 70, 期:13, 页:2251-2256
收录类别: SCI
英文摘要: A series of fully rigid rod-rod type amphiphilic molecules have been constructed by using 4,4'-bipyridin1-ium or 4,4'-bipyridin-1,1'-diium (viologen) as a hydrophilic segment and phenyl, biphenyl or para-tertphenyl as a hydrophobic unit. The crystal structures of four of the molecules have been elucidated. TEM, SEM, AFM, and DLS experiments revealed that these stiff amphiphiles could self-assemble into diverse architectures, including spherical micelles, ultra-long straight nanofibers (>1 mm), and nanotubes in water, which depend on the hydrophilic/hydrophobic fraction ratios of the molecules. (c) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39141
Appears in Collections:物理有机化学研究室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Lin F,Zhou TY,Zhan TG,et al. Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water[J]. Tetrahedron,2014,70(13):2251-2256.
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