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Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water
Alternative Title全刚性棒-棒型两亲分子: 合成、晶体结构以及水相中的自组装性质
Lin F(林沨); Zhou TY(周天佑); Zhan TG(占田广); Zhao X(赵新)
2014
Source PublicationTetrahedron
Volume70Issue:13Pages:2251-2256
AbstractA series of fully rigid rod-rod type amphiphilic molecules have been constructed by using 4,4'-bipyridin1-ium or 4,4'-bipyridin-1,1'-diium (viologen) as a hydrophilic segment and phenyl, biphenyl or para-tertphenyl as a hydrophobic unit. The crystal structures of four of the molecules have been elucidated. TEM, SEM, AFM, and DLS experiments revealed that these stiff amphiphiles could self-assemble into diverse architectures, including spherical micelles, ultra-long straight nanofibers (>1 mm), and nanotubes in water, which depend on the hydrophilic/hydrophobic fraction ratios of the molecules. (c) 2014 Elsevier Ltd. All rights reserved.
Subject Area物理有机化学
DOI10.1016/j.tet.2014.02.029
URL查看原文
Indexed BySCI
Language英语
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39141
Collection物理有机化学研究室
Corresponding AuthorZhao X(赵新)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Lin F,Zhou TY,Zhan TG,et al. Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water[J]. Tetrahedron,2014,70(13):2251-2256.
APA 林沨,周天佑,占田广,&赵新.(2014).Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water.Tetrahedron,70(13),2251-2256.
MLA 林沨,et al."Wholly-rigid rod-rod amphiphiles: synthesis, crystal structures, and self-assembling behavior in water".Tetrahedron 70.13(2014):2251-2256.
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