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学科主题: 金属有机化学
题名: Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes
其他题名: 通过铑催化的双芳基化合物与烯烃的不对称脱氢Heck偶联构建轴手性
作者: Zheng J(郑军)1; You SL(游书力)1
通讯作者: 游书力
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201408805
卷: 53, 期:48, 页:13244-13247
收录类别: SCI
英文摘要: Enantioselective construction of axially chiral biaryls by direct C-H bond functionalization reactions has been realized. Novel axially chiral biaryls were synthesized by the direct C-H bond olefination of biaryl compounds, using a chiral [Cp*Rh-III] catalyst, in good to excellent yields and enantioselectivities. The obtained axially chiral biaryls were found as suitable ligands for rhodium-catalyzed asymmetric conjugate additions.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39128
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.天津化学化工协同创新中心

Recommended Citation:
Zheng J,You SL. Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes[J]. Angew. Chem.-Int. Edit.,2014,53(48):13244-13247.
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