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学科主题: 金属有机化学
题名: Sc(OTf)(3)-Catalyzed Bicyclization of o-Alkynylanilines with Aldehydes: Ring-Fused 1,2-Dihydroquinolines
其他题名: Sc(OTf)3-催化的炔基苯胺和醛的双环化反应
作者: Zhu C(朱灿)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201406959
卷: 53, 期:49, 页:13532-13535
收录类别: SCI
英文摘要: A Sc(OTf)(3)-catalyzed cascade Prins-type cyclization reaction of o-alkynylanilines, bearing a hydroxy or amine functionality, with aldehydes affords 1,2-dihydroquinoline derivatives having an extra fused ring efficiently under mild reaction conditions. It is interesting to observe the reversed reactivity in the highly selective formation of 1,2-dihydroquinoline derivatives instead of the formation of the usually favored indole derivatives.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39127
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.复旦大学

Recommended Citation:
Zhu C,Ma SM. Sc(OTf)(3)-Catalyzed Bicyclization of o-Alkynylanilines with Aldehydes: Ring-Fused 1,2-Dihydroquinolines[J]. Angew. Chem.-Int. Edit.,2014,53(49):13532-13535.
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