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学科主题: 金属有机化学
题名: The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis
其他题名: 环钯作为过渡金属催化剂在有机合成中的应用
作者: Mo DL(莫冬亮)1; Zhang TK(张廷柯)1; Ge GC(葛广存)1; Huang XJ(黄小军)1; Ding CH(丁昌华)1; Dai LX(戴立信)1; Hou XL(侯雪龙)1
通讯作者: 丁昌华 ; 侯雪龙
刊名: Synlett
发表日期: 2014
DOI: 10.1055/s-0034-1379230
卷: 25, 期:19, 页:2686-2702
收录类别: SCI
英文摘要: This account summarizes our recent work on palladacycles in organic synthesis and describes some unique catalytic properties of palladacycles as transition-metal catalysts for some useful transformations. Asymmetric induction has been realized by using chiral palladacycles as transition-metal catalysts. The influence of the C-Pd bond of palladacycles on their catalytic activity has been revealed. The reaction selectivity can be switched by appropriate choice of an sp(2)- or sp(3)-hybridized C,P-palladacycle catalyst. 1Introduction 2The Discovery of the Use of Palladacycles as Transition-Metal Catalysts and Their Applications in Asymmetric Catalysis 3Switch Between Addition and Ring Opening in the Reaction of Oxabicyclic Alkenes with Terminal Alkynes by Catalysis with sp(2)-C,P- or sp(3)-C,P-Palladacycles 4Synthesis of Polysubstituted Furans, Methylenecyclopropanes, and Polycyclic 5H-Benzo[b]azepines through Catalysis by Palladacycles 5Conclusions
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39126
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.广西师范大学

Recommended Citation:
Mo DL,Zhang TK,Ge GC,et al. The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis[J]. Synlett,2014,25(19):2686-2702.
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