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The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis
Alternative Title环钯作为过渡金属催化剂在有机合成中的应用
Mo DL(莫冬亮)1; Zhang TK(张廷柯)1; Ge GC(葛广存)1; Huang XJ(黄小军)1; Ding CH(丁昌华)1; Dai LX(戴立信)1; Hou XL(侯雪龙)1
Source PublicationSynlett
AbstractThis account summarizes our recent work on palladacycles in organic synthesis and describes some unique catalytic properties of palladacycles as transition-metal catalysts for some useful transformations. Asymmetric induction has been realized by using chiral palladacycles as transition-metal catalysts. The influence of the C-Pd bond of palladacycles on their catalytic activity has been revealed. The reaction selectivity can be switched by appropriate choice of an sp(2)- or sp(3)-hybridized C,P-palladacycle catalyst. 1Introduction 2The Discovery of the Use of Palladacycles as Transition-Metal Catalysts and Their Applications in Asymmetric Catalysis 3Switch Between Addition and Ring Opening in the Reaction of Oxabicyclic Alkenes with Terminal Alkynes by Catalysis with sp(2)-C,P- or sp(3)-C,P-Palladacycles 4Synthesis of Polysubstituted Furans, Methylenecyclopropanes, and Polycyclic 5H-Benzo[b]azepines through Catalysis by Palladacycles 5Conclusions
Subject Area金属有机化学
Indexed BySCI
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Document Type期刊论文
Corresponding AuthorDing CH(丁昌华); Hou XL(侯雪龙)
Recommended Citation
GB/T 7714
Mo DL,Zhang TK,Ge GC,et al. The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis[J]. Synlett,2014,25(19):2686-2702.
APA 莫冬亮.,张廷柯.,葛广存.,黄小军.,丁昌华.,...&侯雪龙.(2014).The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis.Synlett,25(19),2686-2702.
MLA 莫冬亮,et al."The Applications of Palladacycles as Transition-Metal Catalysts in Organic Synthesis".Synlett 25.19(2014):2686-2702.
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