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学科主题: 金属有机化学
题名: Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F
其他题名: 不对称合成3,3,5,5-tetrasubstituted 1,2-dioxolanes: 全合成epiplakinic acid F
作者: Tian XY(田湘寅)1; Han JW(韩建伟)1; Zhao Q(赵琼)1; Huang NZ(黄乃正)1
通讯作者: 黄乃正
刊名: Org. Biomol. Chem.
发表日期: 2014
DOI: 10.1039/c4ob00448e
卷: 12, 期:22, 页:3686-3700
收录类别: SCI
英文摘要: The first enantioselective total synthesis of epiplakinic acid F (1) was achieved through a pivotal step involving a radical-mediated asymmetric peroxidation of vinylcyclopropanes with molecular oxygen to construct highly substituted 1,2-dioxolanes. Subsequent conversions of the chiral 1,2-dioxolanes led to total synthesis of epiplakinic acid F (1) and the confirmation of its absolute configuration. The enantiomer of epiplakinic acid F methyl ester (2) was also prepared.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39125
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.香港中文大学

Recommended Citation:
Tian XY,Han JW,Zhao Q,et al. Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F[J]. Org. Biomol. Chem.,2014,12(22):3686-3700.
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