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Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F
Alternative Title不对称合成3,3,5,5-tetrasubstituted 1,2-dioxolanes: 全合成epiplakinic acid F
Tian XY(田湘寅)1; Han JW(韩建伟)1; Zhao Q(赵琼)1; Huang NZ(黄乃正)1
2014
Source PublicationOrg. Biomol. Chem.
Volume12Issue:22Pages:3686-3700
AbstractThe first enantioselective total synthesis of epiplakinic acid F (1) was achieved through a pivotal step involving a radical-mediated asymmetric peroxidation of vinylcyclopropanes with molecular oxygen to construct highly substituted 1,2-dioxolanes. Subsequent conversions of the chiral 1,2-dioxolanes led to total synthesis of epiplakinic acid F (1) and the confirmation of its absolute configuration. The enantiomer of epiplakinic acid F methyl ester (2) was also prepared.
Subject Area金属有机化学
DOI10.1039/c4ob00448e
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Indexed BySCI
Language英语
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Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39125
Collection金属有机化学国家重点实验室
Corresponding AuthorHuang NZ(黄乃正)
Affiliation1.中科院上海有机化学研究所
2.香港中文大学
Recommended Citation
GB/T 7714
Tian XY,Han JW,Zhao Q,et al. Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F[J]. Org. Biomol. Chem.,2014,12(22):3686-3700.
APA 田湘寅,韩建伟,赵琼,&黄乃正.(2014).Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F.Org. Biomol. Chem.,12(22),3686-3700.
MLA 田湘寅,et al."Asymmetric synthesis of 3,3,5,5-tetrasubstituted 1,2-dioxolanes: total synthesis of epiplakinic acid F".Org. Biomol. Chem. 12.22(2014):3686-3700.
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