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Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes
Alternative Title钴催化剂催化的1,1-二取代芳基烯烃的对映选择性硼氢化反应
Zhang L(张雷); Zuo ZQ(左自青); Wan XL(万小龙); Huang Z(黄正)
2014
Source PublicationJ. Am. Chem. Soc.
Volume136Issue:44Pages:15501-15504
AbstractWe report the synthesis of cobalt complexes of novel iminopyridine-oxazoline (IPO) ligands and their application to the asymmetric hydroboration of 1,1-disubstituted aryl alkenes. The new catalysts afforded alpha-alkyl-beta-pinacolatoboranes with exclusive regioselectivity in high yields with up to 99.5% ee. Furthermore, we have applied this method to an efficient synthesis of naproxen.
Subject Area金属有机化学
DOI10.1021/ja5093908
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Indexed BySCI
Language英语
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Cited Times:132[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39123
Collection金属有机化学国家重点实验室
Corresponding AuthorHuang Z(黄正)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhang L,Zuo ZQ,Wan XL,et al. Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes[J]. J. Am. Chem. Soc.,2014,136(44):15501-15504.
APA 张雷,左自青,万小龙,&黄正.(2014).Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes.J. Am. Chem. Soc.,136(44),15501-15504.
MLA 张雷,et al."Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes".J. Am. Chem. Soc. 136.44(2014):15501-15504.
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