SIOC OpenIR  > 金属有机化学国家重点实验室
Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes
Alternative Title钴催化剂催化的1,1-二取代芳基烯烃的对映选择性硼氢化反应
Zhang L(张雷); Zuo ZQ(左自青); Wan XL(万小龙); Huang Z(黄正)
Source PublicationJ. Am. Chem. Soc.
AbstractWe report the synthesis of cobalt complexes of novel iminopyridine-oxazoline (IPO) ligands and their application to the asymmetric hydroboration of 1,1-disubstituted aryl alkenes. The new catalysts afforded alpha-alkyl-beta-pinacolatoboranes with exclusive regioselectivity in high yields with up to 99.5% ee. Furthermore, we have applied this method to an efficient synthesis of naproxen.
Subject Area金属有机化学
Indexed BySCI
Citation statistics
Document Type期刊论文
Corresponding AuthorHuang Z(黄正)
Recommended Citation
GB/T 7714
Zhang L,Zuo ZQ,Wan XL,et al. Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes[J]. J. Am. Chem. Soc.,2014,136(44):15501-15504.
APA 张雷,左自青,万小龙,&黄正.(2014).Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes.J. Am. Chem. Soc.,136(44),15501-15504.
MLA 张雷,et al."Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes".J. Am. Chem. Soc. 136.44(2014):15501-15504.
Files in This Item:
File Name/Size DocType Version Access License
2014534.pdf(594KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[张雷]'s Articles
[左自青]'s Articles
[万小龙]'s Articles
Baidu academic
Similar articles in Baidu academic
[张雷]'s Articles
[左自青]'s Articles
[万小龙]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[张雷]'s Articles
[左自青]'s Articles
[万小龙]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.