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Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes
Alternative Title钯催化芳基碘的C-H三氟乙基化和Heck串联反应: 高效合成邻位三氟乙基化的苯乙烯类化合物
Zhang H(张浩); Chen PH(陈品红); Liu GS(刘国生)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:38Pages:10174-10178
AbstractA palladium-catalyzed selective C-H bond trifluoroethylation of aryl iodides has been explored. The reaction allows for the efficient synthesis of a variety of ortho-trifluoroethyl-substituted styrenes. Preliminary mechanistic studies indicate that the reaction might involve a key Pd-IV intermediate, which is generated through the rate-determining oxidative addition of CF3CH2I to a palladacycle; the bulky nature of CF3CH2I influences the reactivity. Reductive elimination from the Pd-IV complex then leads to the formation of the aryl-CH2CF3 bond.
Subject Area金属有机化学
DOI10.1002/anie.201403793
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Indexed BySCI
Language英语
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Cited Times:86[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39114
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu GS(刘国生)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhang H,Chen PH,Liu GS. Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes[J]. Angew. Chem.-Int. Edit.,2014,53(38):10174-10178.
APA 张浩,陈品红,&刘国生.(2014).Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes.Angew. Chem.-Int. Edit.,53(38),10174-10178.
MLA 张浩,et al."Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes".Angew. Chem.-Int. Edit. 53.38(2014):10174-10178.
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