SIOC OpenIR  > 金属有机化学国家重点实验室
Phosphine-Catalyzed Annulations of 4,4-Dicyano-2-Methylenebut-3-enoates with Maleimides and Maleic Anhydride
其他题名膦催化的贫电子共轭二烯和马来酰亚胺和马来酸酐的环化反应
Zhang XN(张肖楠); Chen GQ(陈根强); Tang XY(唐翔鹰); Wei Y(魏音); Shi M(施敏)
2014
发表期刊Angew. Chem.-Int. Edit.
卷号53期号:40页码:10768-10773
摘要A novel phosphine-catalyzed [4+1] annulation of maleimides with 4,4-dicyano-2-methylenebut-3-enoates has been developed to afford spirocyclic products, and the maleimides serves as C-1 synthons. Moreover, a phosphinecatalyzed formal [3+2] annulation between 4,4-dicyano-2-methylenebut-3-enoates and maleic anhydride has been also achieved, and maleic anhydride behaved as a C-3 synthon in the reaction, thus efficiently affording the functionalized cyclopentenones. A stable phosphinium-containing zwitterionic compound is the key reactive intermediate in both annulations and was successfully isolated. Plausible mechanisms have been proposed on the basis of control experiments and deuterium-labeling experiments.
学科领域金属有机化学
DOI10.1002/anie.201406100
URL查看原文
收录类别SCI
语种英语
引用统计
被引频次:20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39112
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
作者单位中科院上海有机化学研究所
推荐引用方式
GB/T 7714
Zhang XN,Chen GQ,Tang XY,et al. Phosphine-Catalyzed Annulations of 4,4-Dicyano-2-Methylenebut-3-enoates with Maleimides and Maleic Anhydride[J]. Angew. Chem.-Int. Edit.,2014,53(40):10768-10773.
APA 张肖楠,陈根强,唐翔鹰,魏音,&施敏.(2014).Phosphine-Catalyzed Annulations of 4,4-Dicyano-2-Methylenebut-3-enoates with Maleimides and Maleic Anhydride.Angew. Chem.-Int. Edit.,53(40),10768-10773.
MLA 张肖楠,et al."Phosphine-Catalyzed Annulations of 4,4-Dicyano-2-Methylenebut-3-enoates with Maleimides and Maleic Anhydride".Angew. Chem.-Int. Edit. 53.40(2014):10768-10773.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2014474.pdf(447KB)期刊论文作者接受稿开放获取CC BY-NC-SA请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[张肖楠]的文章
[陈根强]的文章
[唐翔鹰]的文章
百度学术
百度学术中相似的文章
[张肖楠]的文章
[陈根强]的文章
[唐翔鹰]的文章
必应学术
必应学术中相似的文章
[张肖楠]的文章
[陈根强]的文章
[唐翔鹰]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。