SIOC OpenIR  > 金属有机化学国家重点实验室
Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex
Alternative Title钪膦宾配合物对Pinacolborane 和 Catecholborane 的B-O断裂
Wang W(王薇)1; Lv YD(吕英东)1; Gou XF(苟小锋)1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1
2014
Source PublicationChin. J. Chem.
Volume32Issue:8Pages:752-756
AbstractReactions of bis-scandium bridged phosphinidene complex, [LSc(mu-PAr)](2) (L=MeC(NDIPP)CHC(Me)(NCH2CH2N(Pr-i)(2)), DIPP = 2,6-(Pr-i)(2)C6H3; Ar = 2,6-Me2C6H3) (1), with pinacolborane, catecholborane, and 9-borabicyclo[3.3.1]nonane (9-BBN) are reported. Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate (2) and catecholate (3), showing B-O bond cleavage. These two scandium complexes contain an unusual [P(Ar)B(H)P(Ar)](2-) dianion, which displays mu-eta(2)eta(2) coordination model. On the other hand, reaction of complex 1 with 9-BBN affords the B-H bond cleavage product, 1,3-diphospha-2,4-diboracyclobutane (4).
Subject Area金属有机化学
DOI10.1002/cjoc.201400150
URL查看原文
Indexed BySCI
Language英语
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39109
Collection金属有机化学国家重点实验室
Corresponding AuthorGou XF(苟小锋); Chen YF(陈耀峰)
Affiliation1.西北大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Wang W,Lv YD,Gou XF,et al. Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex[J]. Chin. J. Chem.,2014,32(8):752-756.
APA 王薇,吕英东,苟小锋,冷雪冰,&陈耀峰.(2014).Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex.Chin. J. Chem.,32(8),752-756.
MLA 王薇,et al."Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex".Chin. J. Chem. 32.8(2014):752-756.
Files in This Item:
File Name/Size DocType Version Access License
2014442.pdf(1331KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[王薇]'s Articles
[吕英东]'s Articles
[苟小锋]'s Articles
Baidu academic
Similar articles in Baidu academic
[王薇]'s Articles
[吕英东]'s Articles
[苟小锋]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[王薇]'s Articles
[吕英东]'s Articles
[苟小锋]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.