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学科主题: 金属有机化学
题名: Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex
其他题名: 钪膦宾配合物对Pinacolborane 和 Catecholborane 的B-O断裂
作者: Wang W(王薇)1; Lv YD(吕英东)1; Gou XF(苟小锋)1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1
通讯作者: 苟小锋 ; 陈耀峰
刊名: Chin. J. Chem.
发表日期: 2014
DOI: 10.1002/cjoc.201400150
卷: 32, 期:8, 页:752-756
收录类别: SCI
英文摘要: Reactions of bis-scandium bridged phosphinidene complex, [LSc(mu-PAr)](2) (L=MeC(NDIPP)CHC(Me)(NCH2CH2N(Pr-i)(2)), DIPP = 2,6-(Pr-i)(2)C6H3; Ar = 2,6-Me2C6H3) (1), with pinacolborane, catecholborane, and 9-borabicyclo[3.3.1]nonane (9-BBN) are reported. Complex 1 reacts with pinacolborane and catecholborane to give scandium pinacolate (2) and catecholate (3), showing B-O bond cleavage. These two scandium complexes contain an unusual [P(Ar)B(H)P(Ar)](2-) dianion, which displays mu-eta(2)eta(2) coordination model. On the other hand, reaction of complex 1 with 9-BBN affords the B-H bond cleavage product, 1,3-diphospha-2,4-diboracyclobutane (4).
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39109
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.西北大学
2.中科院上海有机化学研究所

Recommended Citation:
Wang W,Lv YD,Gou XF,et al. Boron-Oxygen Bond Cleavage of Pinacolborane and Catecholborane Mediated by a Scandium Phosphinidene Complex[J]. Chin. J. Chem.,2014,32(8):752-756.
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