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学科主题: 金属有机化学
题名: Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G
其他题名: 涉及1,2-重排的金催化呋喃/炔串联环化反应: 多官能团化1-萘醇的合成及其在Wailupemycin G合成中的应用
作者: Chen YF(陈宜峰); Wang L(王璐); Sun N(孙宁); Jie X(解鑫); Zhou XB(周小波); Chen HY(陈好益); Li YX(李玉学); Liu YH(刘元红)
通讯作者: 李玉学 ; 刘元红
刊名: Chem.-Eur. J.
发表日期: 2014
DOI: 10.1002/chem.201403113
卷: 20, 期:38, 页:12015-12019
收录类别: SCI
英文摘要: Gold-catalyzed cascade cyclization/ 1,2-rearrangement of 1-(2-furanyl)phenyl propargyl alcohols has been developed, which provides a rapid and efficient access to multisubstituted 1-naphthols bearing an enal or enone moiety with high stereoselectivity. The (Z)- or (E)-stereochemistry can be easily controlled by choosing protected- or non-protected substrates. The utility of the methodology has been illustrated in the first total synthesis of wailupemycin G.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39103
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Chen YF,Wang L,Sun N,et al. Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G[J]. Chem.-Eur. J.,2014,20(38):12015-12019.
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