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Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G
Alternative Title涉及1,2-重排的金催化呋喃/炔串联环化反应: 多官能团化1-萘醇的合成及其在Wailupemycin G合成中的应用
Chen YF(陈宜峰); Wang L(王璐); Sun N(孙宁); Jie X(解鑫); Zhou XB(周小波); Chen HY(陈好益); Li YX(李玉学); Liu YH(刘元红)
2014
Source PublicationChem.-Eur. J.
Volume20Issue:38Pages:12015-12019
AbstractGold-catalyzed cascade cyclization/ 1,2-rearrangement of 1-(2-furanyl)phenyl propargyl alcohols has been developed, which provides a rapid and efficient access to multisubstituted 1-naphthols bearing an enal or enone moiety with high stereoselectivity. The (Z)- or (E)-stereochemistry can be easily controlled by choosing protected- or non-protected substrates. The utility of the methodology has been illustrated in the first total synthesis of wailupemycin G.
Subject Area金属有机化学
DOI10.1002/chem.201403113
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39103
Collection金属有机化学国家重点实验室
Corresponding AuthorLi YX(李玉学); Liu YH(刘元红)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Chen YF,Wang L,Sun N,et al. Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G[J]. Chem.-Eur. J.,2014,20(38):12015-12019.
APA 陈宜峰.,王璐.,孙宁.,解鑫.,周小波.,...&刘元红.(2014).Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G.Chem.-Eur. J.,20(38),12015-12019.
MLA 陈宜峰,et al."Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G".Chem.-Eur. J. 20.38(2014):12015-12019.
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