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Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach
Alternative Title催化剂导向的吡咯合成
Chen GQ(陈根强); Zhang XN(张肖楠); Wei Y(魏音); Tang XY(唐翔鹰); Shi M(施敏)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:32Pages:8492-8497
AbstractA novel Ru-0- and Rh-I-catalyzed noncarbonylative and carbonylative cycloisomerization of readily available 3-alkynyl imine derivatives has been developed to provide 3,4-fused or nonfused pyrrole derivatives efficiently in moderate to excellent yields. The key steps involve the formation of a ruthenium carbenoid intermediate or a rhodacycle intermediate, respectively. In these reactions, CO can serve as a ligand or a reagent.
Subject Area金属有机化学
DOI10.1002/anie.201405215
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39093
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Chen GQ,Zhang XN,Wei Y,et al. Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach[J]. Angew. Chem.-Int. Edit.,2014,53(32):8492-8497.
APA 陈根强,张肖楠,魏音,唐翔鹰,&施敏.(2014).Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach.Angew. Chem.-Int. Edit.,53(32),8492-8497.
MLA 陈根强,et al."Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach".Angew. Chem.-Int. Edit. 53.32(2014):8492-8497.
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