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学科主题: 金属有机化学
题名: Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach
其他题名: 催化剂导向的吡咯合成
作者: Chen GQ(陈根强); Zhang XN(张肖楠); Wei Y(魏音); Tang XY(唐翔鹰); Shi M(施敏)
通讯作者: 施敏
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201405215
卷: 53, 期:32, 页:8492-8497
收录类别: SCI
英文摘要: A novel Ru-0- and Rh-I-catalyzed noncarbonylative and carbonylative cycloisomerization of readily available 3-alkynyl imine derivatives has been developed to provide 3,4-fused or nonfused pyrrole derivatives efficiently in moderate to excellent yields. The key steps involve the formation of a ruthenium carbenoid intermediate or a rhodacycle intermediate, respectively. In these reactions, CO can serve as a ligand or a reagent.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39093
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Chen GQ,Zhang XN,Wei Y,et al. Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach[J]. Angew. Chem.-Int. Edit.,2014,53(32):8492-8497.
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