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(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents
Alternative Title氮杂环卡宾、硅二烯支撑的零价铁化合物: 一类新型的低配位零价铁试剂
Zhang HZ(张河中); 欧阳振武; Liu YS(刘月盛); Zhang Q(张强); Wang L(王磊); Deng L(邓亮)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:32Pages:8432-8436
AbstractThe combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of unprecedented low-coordinate iron(0) alkene compounds [LnFe(eta(2) : eta(2)-dvtms)] (L=N-heterocyclic carbene (NHC) or cyclic (alkyl)(amino) carbene (CAAC), n=1 or 2) from the reactions of FeCl2 with alkali-metal reducing agents, free aminocarbene ligands, and dvtms. The iron(0) species deliver their {LnFe0} fragments to perform redox reactions with Ph2SiH2, S-8, Se, and DippN(3), furnishing novel aminocarbene-supported iron(IV) silylene, all-ferrous iron-sulfur/selenium cubanes, and bis(imido) iron(IV) compounds. These conversions demonstrate the potential synthetic utility of the carbene-supported iron(0) complexes as a valuable class of low-coordinate iron(0) reagents.
Subject Area金属有机化学
DOI10.1002/anie.201404677
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Indexed BySCI
Language英语
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Cited Times:38[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39092
Collection金属有机化学国家重点实验室
Corresponding AuthorDeng L(邓亮)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhang HZ,欧阳振武,Liu YS,et al. (Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents[J]. Angew. Chem.-Int. Edit.,2014,53(32):8432-8436.
APA 张河中,欧阳振武,刘月盛,张强,王磊,&邓亮.(2014).(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents.Angew. Chem.-Int. Edit.,53(32),8432-8436.
MLA 张河中,et al."(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents".Angew. Chem.-Int. Edit. 53.32(2014):8432-8436.
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