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学科主题: 金属有机化学
题名: (Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents
其他题名: 氮杂环卡宾、硅二烯支撑的零价铁化合物: 一类新型的低配位零价铁试剂
作者: Zhang HZ(张河中); 欧阳振武; Liu YS(刘月盛); Zhang Q(张强); Wang L(王磊); Deng L(邓亮)
通讯作者: 邓亮
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201404677
卷: 53, 期:32, 页:8432-8436
收录类别: SCI
英文摘要: The combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of unprecedented low-coordinate iron(0) alkene compounds [LnFe(eta(2) : eta(2)-dvtms)] (L=N-heterocyclic carbene (NHC) or cyclic (alkyl)(amino) carbene (CAAC), n=1 or 2) from the reactions of FeCl2 with alkali-metal reducing agents, free aminocarbene ligands, and dvtms. The iron(0) species deliver their {LnFe0} fragments to perform redox reactions with Ph2SiH2, S-8, Se, and DippN(3), furnishing novel aminocarbene-supported iron(IV) silylene, all-ferrous iron-sulfur/selenium cubanes, and bis(imido) iron(IV) compounds. These conversions demonstrate the potential synthetic utility of the carbene-supported iron(0) complexes as a valuable class of low-coordinate iron(0) reagents.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39092
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhang HZ,欧阳振武,Liu YS,et al. (Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents[J]. Angew. Chem.-Int. Edit.,2014,53(32):8432-8436.
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