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Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst
Alternative TitlePd/Sox催化末端烯烃烯丙位C-H键的支链选择性酯化反应
Hiroki Kondo1; Yu F(于峰)1; Junichiro Yamaguchi1; Liu GS(刘国生)1; Kenichiro Itami1
2014
Source PublicationOrg. Lett.
Volume16Issue:16Pages:4212-4215
AbstractA ligand-controlled branch-selective allylic C-H carboxylation through Pd catalysis is described. The developed catalytic system, which consists of Pd(OAc)(2), sulfoxide oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.
Subject Area金属有机化学
DOI10.1021/ol5019135
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39091
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu GS(刘国生); Kenichiro Itami
Affiliation1.日本名古屋大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Hiroki Kondo,Yu F,Junichiro Yamaguchi,et al. Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst[J]. Org. Lett.,2014,16(16):4212-4215.
APA Hiroki Kondo,于峰,Junichiro Yamaguchi,刘国生,&Kenichiro Itami.(2014).Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst.Org. Lett.,16(16),4212-4215.
MLA Hiroki Kondo,et al."Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst".Org. Lett. 16.16(2014):4212-4215.
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