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学科主题: 金属有机化学
题名: Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst
其他题名: Pd/Sox催化末端烯烃烯丙位C-H键的支链选择性酯化反应
作者: Hiroki Kondo1; Yu F(于峰)1; Junichiro Yamaguchi1; Liu GS(刘国生)1; Kenichiro Itami1
通讯作者: 刘国生 ; Kenichiro Itami
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol5019135
卷: 16, 期:16, 页:4212-4215
收录类别: SCI
英文摘要: A ligand-controlled branch-selective allylic C-H carboxylation through Pd catalysis is described. The developed catalytic system, which consists of Pd(OAc)(2), sulfoxide oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39091
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.日本名古屋大学
2.中科院上海有机化学研究所

Recommended Citation:
Hiroki Kondo,Yu F,Junichiro Yamaguchi,et al. Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst[J]. Org. Lett.,2014,16(16):4212-4215.
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