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学科主题: 金属有机化学
题名: Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction
其他题名: 设计合成新的salen配体及其钴和镱络合物: 作为催化剂催化不对称henry反应, 并致使其产物的不对称反转效应
作者: Wu SY(吴生英)1; Tang J(唐俊)1; Han JW(韩建伟)1; Mao D(毛丹)1; Liu X(刘欣)1; Gao S(高省)1; Yu JJ(余建军)1; Wang LM(王利民)1
通讯作者: 韩建伟 ; 王利民
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.05.085
卷: 70, 期:35, 页:5986-5992
收录类别: SCI
英文摘要: Reversal of enantioselectivity in asymmetric Henry reactions was achieved with novel chiral C-2-symmetric salen ligands bearing morpholine moieties by changing the Lewis acid center from Co(II) to Yb(III). The possible transition state models were supported by mass spectrometry experiments. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39090
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.中科院上海有机化学研究所

Recommended Citation:
Wu SY,Tang J,Han JW,et al. Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction[J]. Tetrahedron,2014,70(35):5986-5992.
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