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Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction
Alternative Title设计合成新的salen配体及其钴和镱络合物: 作为催化剂催化不对称henry反应, 并致使其产物的不对称反转效应
Wu SY(吴生英)1; Tang J(唐俊)1; Han JW(韩建伟)1; Mao D(毛丹)1; Liu X(刘欣)1; Gao S(高省)1; Yu JJ(余建军)1; Wang LM(王利民)1
2014
Source PublicationTetrahedron
Volume70Issue:35Pages:5986-5992
AbstractReversal of enantioselectivity in asymmetric Henry reactions was achieved with novel chiral C-2-symmetric salen ligands bearing morpholine moieties by changing the Lewis acid center from Co(II) to Yb(III). The possible transition state models were supported by mass spectrometry experiments. (C) 2014 Elsevier Ltd. All rights reserved.
Subject Area金属有机化学
DOI10.1016/j.tet.2014.05.085
URL查看原文
Indexed BySCI
Language英语
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Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39090
Collection金属有机化学国家重点实验室
Corresponding AuthorHan JW(韩建伟); Wang LM(王利民)
Affiliation1.华东理工大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Wu SY,Tang J,Han JW,et al. Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction[J]. Tetrahedron,2014,70(35):5986-5992.
APA 吴生英.,唐俊.,韩建伟.,毛丹.,刘欣.,...&王利民.(2014).Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction.Tetrahedron,70(35),5986-5992.
MLA 吴生英,et al."Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction".Tetrahedron 70.35(2014):5986-5992.
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