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Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation
Alternative Title钪末端氮宾配合物诱导C-N键的活化和转化
Chu JX(楚甲祥); Zhou QH(周庆海); Li YX(李玉学); Leng XB(冷雪冰); Chen YF(陈耀峰)
2014
Source PublicationSci. China-Chem.
Volume57Issue:8Pages:1098-1105
AbstractThe scandium terminal imido complex supported by a monoanionic tetradentate NNNN ligand, [LSc=N(DIPP)] (L = [MeC(N(DIPP))CHC(Me)(NCH2CH2N(Me)CH2CH2NMe2](-), DIPP = 2,6-( (i) Pr)(2)C6H3) (1), undergoes a C-N bond cleavage at elevated temperature to give a mononuclear scandium anilido intermediate 2a, which subsequently aggregates into a binuclear scandium anilido complex 2. The mononuclear intermediate 2a reacts with alkyne or imine to provide two scandium anilido complexes 3 and 4, which contain a dianionic tetradentate NNNC ligand or a dianionic tetradentate NNNN ligand. DFT calculations on the reaction mechanism of C-N bond cleavage in 1 were also performed.
Subject Area金属有机化学
DOI10.1007/s11426-014-5117-8
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39088
Collection金属有机化学国家重点实验室
Corresponding AuthorLi YX(李玉学); Chen YF(陈耀峰)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Chu JX,Zhou QH,Li YX,et al. Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation[J]. Sci. China-Chem.,2014,57(8):1098-1105.
APA 楚甲祥,周庆海,李玉学,冷雪冰,&陈耀峰.(2014).Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation.Sci. China-Chem.,57(8),1098-1105.
MLA 楚甲祥,et al."Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation".Sci. China-Chem. 57.8(2014):1098-1105.
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