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学科主题: 金属有机化学
题名: Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation
其他题名: 钪末端氮宾配合物诱导C-N键的活化和转化
作者: Chu JX(楚甲祥); Zhou QH(周庆海); Li YX(李玉学); Leng XB(冷雪冰); Chen YF(陈耀峰)
通讯作者: 李玉学 ; 陈耀峰
刊名: Sci. China-Chem.
发表日期: 2014
DOI: 10.1007/s11426-014-5117-8
卷: 57, 期:8, 页:1098-1105
收录类别: SCI
英文摘要: The scandium terminal imido complex supported by a monoanionic tetradentate NNNN ligand, [LSc=N(DIPP)] (L = [MeC(N(DIPP))CHC(Me)(NCH2CH2N(Me)CH2CH2NMe2](-), DIPP = 2,6-( (i) Pr)(2)C6H3) (1), undergoes a C-N bond cleavage at elevated temperature to give a mononuclear scandium anilido intermediate 2a, which subsequently aggregates into a binuclear scandium anilido complex 2. The mononuclear intermediate 2a reacts with alkyne or imine to provide two scandium anilido complexes 3 and 4, which contain a dianionic tetradentate NNNC ligand or a dianionic tetradentate NNNN ligand. DFT calculations on the reaction mechanism of C-N bond cleavage in 1 were also performed.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39088
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Chu JX,Zhou QH,Li YX,et al. Scandium terminal imido complex induced intramolecular C-N bond cleavage and transformation[J]. Sci. China-Chem.,2014,57(8):1098-1105.
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