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Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution
Alternative Title钯(II)催化的分子间C-H键直接碘化: 通过动力学拆分合成轴手性化合物的一种有效方法
Gao DW(高得伟); Gu Q(顾庆); You SL(游书力)
2014
Source PublicationACS Catal.
Volume4Issue:8Pages:2741-2745
AbstractAn efficient protocol to synthesize axially chiral compounds via kinetic resolution by Pd(II)-catalyzed direct C H iodination was realized (up to s = 27). The iodide product could be easily transformed to aryl-substituted pyridine N-oxides via the Suzuki Miyaura coupling, which proved to be a suitable catalyst in asymmetric allylation of benzaldehyde with allyltrichlorosilane.
Subject Area金属有机化学
DOI10.1021/cs500813z
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39084
Collection金属有机化学国家重点实验室
Corresponding AuthorGu Q(顾庆); You SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Gao DW,Gu Q,You SL. Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution[J]. ACS Catal.,2014,4(8):2741-2745.
APA 高得伟,顾庆,&游书力.(2014).Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution.ACS Catal.,4(8),2741-2745.
MLA 高得伟,et al."Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution".ACS Catal. 4.8(2014):2741-2745.
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