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学科主题: 金属有机化学
题名: Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution
其他题名: 钯(II)催化的分子间C-H键直接碘化: 通过动力学拆分合成轴手性化合物的一种有效方法
作者: Gao DW(高得伟); Gu Q(顾庆); You SL(游书力)
通讯作者: 顾庆 ; 游书力
刊名: ACS Catal.
发表日期: 2014
DOI: 10.1021/cs500813z
卷: 4, 期:8, 页:2741-2745
收录类别: SCI
英文摘要: An efficient protocol to synthesize axially chiral compounds via kinetic resolution by Pd(II)-catalyzed direct C H iodination was realized (up to s = 27). The iodide product could be easily transformed to aryl-substituted pyridine N-oxides via the Suzuki Miyaura coupling, which proved to be a suitable catalyst in asymmetric allylation of benzaldehyde with allyltrichlorosilane.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39084
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Gao DW,Gu Q,You SL. Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution[J]. ACS Catal.,2014,4(8):2741-2745.
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