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学科主题: 金属有机化学
题名: Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations
其他题名: 碳硼炔与富烯的D-A反应: 碳硼烷并冰片烯的合成与转化
作者: Zhang J(张洁)1; Qiu ZZ(邱早早)1; Xu PF(许鹏飞)1; Xie ZW(谢作伟)1
通讯作者: 邱早早 ; 许鹏飞
刊名: ChemPlusChem
发表日期: 2014
DOI: 10.1002/cplu.201402129
卷: 79, 期:7, 页:1044-1052
收录类别: SCI
英文摘要: o-Carboryne (1,2-dehydro-o-carborane) generated in situ from the precursor 1-iodo-2-lithio-o-carborane reacts with 6,6'-diarylfulvenes to give a series of carboranonorbornadienes in moderate yields with excellent regioselectivity. The resultant [4+2] cycloadducts can be further derivatized, thus leading to the formation of a variety of highly functionalized carboranes. This study shows that such Diels-Alder reaction serves as a convenient method for the preparation of a new class of multifunctionalized o-carborane derivatives that might find applications in medicine and materials science.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39082
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.兰州大学
3.香港中文大学

Recommended Citation:
Zhang J,Qiu ZZ,Xu PF,et al. Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations[J]. ChemPlusChem,2014,79(7):1044-1052.
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