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Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations
Alternative Title碳硼炔与富烯的D-A反应: 碳硼烷并冰片烯的合成与转化
Zhang J(张洁)1; Qiu ZZ(邱早早)1; Xu PF(许鹏飞)1; Xie ZW(谢作伟)1
2014
Source PublicationChemPlusChem
Volume79Issue:7Pages:1044-1052
Abstracto-Carboryne (1,2-dehydro-o-carborane) generated in situ from the precursor 1-iodo-2-lithio-o-carborane reacts with 6,6'-diarylfulvenes to give a series of carboranonorbornadienes in moderate yields with excellent regioselectivity. The resultant [4+2] cycloadducts can be further derivatized, thus leading to the formation of a variety of highly functionalized carboranes. This study shows that such Diels-Alder reaction serves as a convenient method for the preparation of a new class of multifunctionalized o-carborane derivatives that might find applications in medicine and materials science.
Subject Area金属有机化学
DOI10.1002/cplu.201402129
URL查看原文
Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39082
Collection金属有机化学国家重点实验室
Corresponding AuthorQiu ZZ(邱早早); Xu PF(许鹏飞)
Affiliation1.中科院上海有机化学研究所
2.兰州大学
3.香港中文大学
Recommended Citation
GB/T 7714
Zhang J,Qiu ZZ,Xu PF,et al. Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations[J]. ChemPlusChem,2014,79(7):1044-1052.
APA 张洁,邱早早,许鹏飞,&谢作伟.(2014).Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations.ChemPlusChem,79(7),1044-1052.
MLA 张洁,et al."Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations".ChemPlusChem 79.7(2014):1044-1052.
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