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Phosphine-catalyzed asymmetric [4+1] annulation of activated alpha,beta-unsaturated ketones with Morita-Baylis-Hillman carbonates: enantioselective synthesis of spirooxindoles containing two adjacent quaternary stereocenters
Alternative Title膦催化的MBH产物和a,b-不饱和酮的[4+1]环加成反应, 高对映选择性地合成螺环氧化吲哚
Hu FL(胡方乐); Wei Y(魏音); Shi M(施敏)
2014
Source PublicationChem. Commun.
Volume50Issue:64Pages:8912-8914
AbstractThe asymmetric [4+1] annulation of activated alpha,beta-unsaturated ketones with MBH carbonates catalyzed by bifunctional thiourea-phosphine catalysts derived from an axially chiral binaphthyl scaffold has been developed, giving spirooxindoles with two adjacent quaternary stereocenters in good yields with high enantioselectivities and moderate diastereoselectivities under mild conditions.
Subject Area金属有机化学
DOI10.1039/c4cc03479a
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Indexed BySCI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39080
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Hu FL,Wei Y,Shi M. Phosphine-catalyzed asymmetric [4+1] annulation of activated alpha,beta-unsaturated ketones with Morita-Baylis-Hillman carbonates: enantioselective synthesis of spirooxindoles containing two adjacent quaternary stereocenters[J]. Chem. Commun.,2014,50(64):8912-8914.
APA 胡方乐,魏音,&施敏.(2014).Phosphine-catalyzed asymmetric [4+1] annulation of activated alpha,beta-unsaturated ketones with Morita-Baylis-Hillman carbonates: enantioselective synthesis of spirooxindoles containing two adjacent quaternary stereocenters.Chem. Commun.,50(64),8912-8914.
MLA 胡方乐,et al."Phosphine-catalyzed asymmetric [4+1] annulation of activated alpha,beta-unsaturated ketones with Morita-Baylis-Hillman carbonates: enantioselective synthesis of spirooxindoles containing two adjacent quaternary stereocenters".Chem. Commun. 50.64(2014):8912-8914.
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