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Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions
Alternative Title通过铱催化的烯丙基胺化反应实现的吡啶和吡嗪的直接不对称去芳构化
Yang ZP(杨泽鹏); Wu QF(武庆锋); You SL(游书力)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:27Pages:6986-6989
AbstractThe first iridium-catalyzed intramolecular asymmetric allylic dearomatization reaction of pyridines and pyrazines has been realized. 2,3-Dihydroindolizine and 6,7-dihydropyrrolo[1,2-a]pyrazine derivatives were obtained with excellent yields and enantioselectivity. This methodology features dearomatization by direct N-allylic alkylation of pyridines or pyrazines under mild reaction conditions.
Subject Area金属有机化学
DOI10.1002/anie.201404286
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Indexed BySCI
Language英语
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Cited Times:52[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39071
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yang ZP,Wu QF,You SL. Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions[J]. Angew. Chem.-Int. Edit.,2014,53(27):6986-6989.
APA 杨泽鹏,武庆锋,&游书力.(2014).Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions.Angew. Chem.-Int. Edit.,53(27),6986-6989.
MLA 杨泽鹏,et al."Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions".Angew. Chem.-Int. Edit. 53.27(2014):6986-6989.
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