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学科主题: 金属有机化学
题名: Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates
其他题名: 钯催化α-氟代膦酸酯的高区域, 非对映和对映选择性的烯丙基烷基化反应
作者: Huang Y(黄莹)1; Zhang QS(张卿菘)1; Fang P(方萍)1; Chen TG(陈铁根)1; Zhu J(朱军)1; Hou XL(侯雪龙)1
通讯作者: 方萍 ; 侯雪龙
刊名: Chem. Commun.
发表日期: 2014
DOI: 10.1039/c4cc02158d
卷: 50, 期:51, 页:6751-6753
收录类别: SCI
英文摘要: Highly efficient Pd-catalyzed asymmetric allylic alkylation reaction of ethyl-2-fluoro-2-(diethoxyphosphoryl) acetate with monosubstituted allylic substrates has been developed, affording corresponding alpha-fluorophosphonates with two chiral centers in high regio-, diastereo- and enantio-selectivities. The usefulness of the products in organic synthesis has been demonstrated.
语种: 英语
相关网址: 查看原文
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39070
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.厦门大学

Recommended Citation:
Huang Y,Zhang QS,Fang P,et al. Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates[J]. Chem. Commun.,2014,50(51):6751-6753.
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