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Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates
Alternative Title钯催化α-氟代膦酸酯的高区域, 非对映和对映选择性的烯丙基烷基化反应
Huang Y(黄莹)1; Zhang QS(张卿菘)1; Fang P(方萍)1; Chen TG(陈铁根)1; Zhu J(朱军)1; Hou XL(侯雪龙)1
2014
Source PublicationChem. Commun.
Volume50Issue:51Pages:6751-6753
AbstractHighly efficient Pd-catalyzed asymmetric allylic alkylation reaction of ethyl-2-fluoro-2-(diethoxyphosphoryl) acetate with monosubstituted allylic substrates has been developed, affording corresponding alpha-fluorophosphonates with two chiral centers in high regio-, diastereo- and enantio-selectivities. The usefulness of the products in organic synthesis has been demonstrated.
Subject Area金属有机化学
DOI10.1039/c4cc02158d
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Indexed BySCI
Language英语
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Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39070
Collection金属有机化学国家重点实验室
Corresponding AuthorFang P(方萍); Hou XL(侯雪龙)
Affiliation1.中科院上海有机化学研究所
2.厦门大学
Recommended Citation
GB/T 7714
Huang Y,Zhang QS,Fang P,et al. Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates[J]. Chem. Commun.,2014,50(51):6751-6753.
APA 黄莹,张卿菘,方萍,陈铁根,朱军,&侯雪龙.(2014).Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates.Chem. Commun.,50(51),6751-6753.
MLA 黄莹,et al."Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of alpha-fluorophosphonates".Chem. Commun. 50.51(2014):6751-6753.
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