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Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates
Alternative Title1-双(三氟甲基)膦基-1'-恶唑啉二茂铁配体的合成和它们在钯催化的单取代烯丙基底物的区域选择性以及对映选择性烯丙基烷基化中的应用
Lai ZW(赖增伟)1; Yang RF(杨荣飞)1; Ye KY(叶克印)1; SUN HONGBIN1; You SL(游书力)1
2014
Source PublicationBeilstein J. Org. Chem.
Volume10Pages:1261-1266
AbstractA class of novel, easily accessible and air-stable 1-[bis(trifluoromethyl)phosphine]-1'-oxazolinylferrocene ligands has been synthesized from ferrocene. It became apparent that these ligands can be used in the regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates in a highly efficient manner. Excellent regio- and enantioselectivity could be obtained for a wide range of substrates.
Subject Area金属有机化学
DOI10.3762/bjoc.10.126
URL查看原文
Indexed BySCI
Language英语
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Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39068
Collection金属有机化学国家重点实验室
Corresponding AuthorSUN HONGBIN; You SL(游书力)
Affiliation1.中科院上海有机化学研究所
2.中国药科大学
3.康龙化成(北京)新药技术有限公司
Recommended Citation
GB/T 7714
Lai ZW,Yang RF,Ye KY,et al. Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates[J]. Beilstein J. Org. Chem.,2014,10:1261-1266.
APA 赖增伟,杨荣飞,叶克印,SUN HONGBIN,&游书力.(2014).Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates.Beilstein J. Org. Chem.,10,1261-1266.
MLA 赖增伟,et al."Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates".Beilstein J. Org. Chem. 10(2014):1261-1266.
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