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Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex
Alternative Title铱螯型络合物选择性催化烷烃和杂环化合物的转移脱氢反应
Yao WB(姚武冰); Zhang YX(张宇轩); Jia XQ(贾香清); Huang Z(黄正)
2014
Source PublicationAngew. Chem.-Int. Edit.
Volume53Issue:5Pages:1390-1394
AbstractCatalytic alkane dehydrogenation is a reaction with tremendous potential for application. We describe a highly active PSCOP-pincer iridium catalyst for transfer dehydrogenation of cyclic and linear alkanes. The dehydrogenation of linear alkanes occurs under relatively mild conditions with high regioselectivity for alpha-olefin formation. In addition, the catalyst system is very effective in the dehydrogenation of heterocycles to form heteroarenes and olefinic products.
Subject Area金属有机化学
DOI10.1002/anie.201306559
URL查看原文
Indexed BySCI
Language英语
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Cited Times:76[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39067
Collection金属有机化学国家重点实验室
Corresponding AuthorHuang Z(黄正)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yao WB,Zhang YX,Jia XQ,et al. Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex[J]. Angew. Chem.-Int. Edit.,2014,53(5):1390-1394.
APA 姚武冰,张宇轩,贾香清,&黄正.(2014).Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex.Angew. Chem.-Int. Edit.,53(5),1390-1394.
MLA 姚武冰,et al."Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex".Angew. Chem.-Int. Edit. 53.5(2014):1390-1394.
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