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Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions
Alternative Title金催化炔-亚乙烯基环丙烷的环异构化反应-3碳合成子的[3+2]环加成反应
Yuan W(袁渭); Tang XY(唐翔鹰); Wei Y(魏音); Shi M(施敏)
2014
Source PublicationChem.-Eur. J.
Volume20Issue:11Pages:3198-3204
AbstractA novel type of yne-vinylidenecyclopropanes (VDCPs) has been synthesized and applied in gold-catalyzed cycloisomerization reactions. It was found that these compounds can undergo an intramolecular cycloisomerization and perform as a three-carbon synthon for [3+2] cycloaddition under gold catalysis to give fused [4.3.0] and [5.3.0] bicyclic derivatives and VDCP rearranged products in moderated to good yields under mild conditions. The substrate scope of these novel transformations has been explored and plausible reaction mechanisms have been presented on the basis of deuterium labeling experiments and DFT calculations.
Subject Area金属有机化学
DOI10.1002/chem.201304579
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Indexed BySCI
Language英语
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Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39066
Collection金属有机化学国家重点实验室
Corresponding AuthorWei Y(魏音); Shi M(施敏)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yuan W,Tang XY,Wei Y,et al. Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions[J]. Chem.-Eur. J.,2014,20(11):3198-3204.
APA 袁渭,唐翔鹰,魏音,&施敏.(2014).Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions.Chem.-Eur. J.,20(11),3198-3204.
MLA 袁渭,et al."Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions".Chem.-Eur. J. 20.11(2014):3198-3204.
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