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学科主题: 金属有机化学
题名: Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions
其他题名: 通过铱催化的烯丙基胺化/过渡金属催化环化反应区域选择性以及对映选择性地合成N-烯丙基吲哚
作者: Ye KY(叶克印); Dai LX(戴立信); You SL(游书力)
通讯作者: 游书力
刊名: Chem.-Eur. J.
发表日期: 2014
DOI: 10.1002/chem.201400026
卷: 20, 期:11, 页:3040-3044
收录类别: SCI
英文摘要: Regio- and enantioselective synthesis of N-allylindoles was realized through an iridium-catalyzed asymmetric allylic amination reaction with 2-alkynylanilines and subsequent transition-metal-catalyzed cyclization reactions. The highly enantioenriched allylic amines prepared from Ir-catalysis were treated with catalytic amount of NaAuCl(4)2H(2)O or PdCl2 providing various substituted N-allylindoles in excellent yields and enantioselectivities.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39065
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Ye KY,Dai LX,You SL. Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions[J]. Chem.-Eur. J.,2014,20(11):3040-3044.
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