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Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions
Alternative Title通过铱催化的烯丙基胺化/过渡金属催化环化反应区域选择性以及对映选择性地合成N-烯丙基吲哚
Ye KY(叶克印); Dai LX(戴立信); You SL(游书力)
2014
Source PublicationChem.-Eur. J.
Volume20Issue:11Pages:3040-3044
AbstractRegio- and enantioselective synthesis of N-allylindoles was realized through an iridium-catalyzed asymmetric allylic amination reaction with 2-alkynylanilines and subsequent transition-metal-catalyzed cyclization reactions. The highly enantioenriched allylic amines prepared from Ir-catalysis were treated with catalytic amount of NaAuCl(4)2H(2)O or PdCl2 providing various substituted N-allylindoles in excellent yields and enantioselectivities.
Subject Area金属有机化学
DOI10.1002/chem.201400026
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Indexed BySCI
Language英语
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Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39065
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Ye KY,Dai LX,You SL. Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions[J]. Chem.-Eur. J.,2014,20(11):3040-3044.
APA 叶克印,戴立信,&游书力.(2014).Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions.Chem.-Eur. J.,20(11),3040-3044.
MLA 叶克印,et al."Regio-and Enantioselective Synthesis of N-Allylindoles by Iridium-Catalyzed Allylic Amination/Transition-Metal-Catalyzed Cyclization Reactions".Chem.-Eur. J. 20.11(2014):3040-3044.
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