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Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics
Alternative Title过渡金属介导三组份串联反应: 碳硼烷硼与芳烃间硼-碳(sp2)偶联及碳硼烷并三环化合物的合成
Quan YJ(全杨健)1; Qiu ZZ(邱早早)1; Xie ZW(谢作伟)1
2014
Source PublicationJ. Am. Chem. Soc.
Volume136Issue:21Pages:7599-7602
AbstractZirconium/nickel comediated one-pot three-component cascade cyclization of carboryne, alkene, and 2-bromophenyltrimethylsilylacetylene has been achieved, leading to the formation of a series of C,C,B-substituted carborane-fused tricyclics. On the basis of experimental results, a plausible mechanism is proposed including [2 + 2 + 1] cross-cyclotrimerization followed by intramolecular direct selective cage B-C(sp(2)) coupling. This represents the first example of direct cage B-C(phenyl) coupling via cage B-H activation.
Subject Area金属有机化学
DOI10.1021/ja503489b
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Indexed BySCI
Language英语
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Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39063
Collection金属有机化学国家重点实验室
Corresponding AuthorXie ZW(谢作伟)
Affiliation1.香港中文大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Quan YJ,Qiu ZZ,Xie ZW. Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics[J]. J. Am. Chem. Soc.,2014,136(21):7599-7602.
APA 全杨健,邱早早,&谢作伟.(2014).Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics.J. Am. Chem. Soc.,136(21),7599-7602.
MLA 全杨健,et al."Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics".J. Am. Chem. Soc. 136.21(2014):7599-7602.
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