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学科主题: 金属有机化学
题名: Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics
其他题名: 过渡金属介导三组份串联反应: 碳硼烷硼与芳烃间硼-碳(sp2)偶联及碳硼烷并三环化合物的合成
作者: Quan YJ(全杨健)1; Qiu ZZ(邱早早)1; Xie ZW(谢作伟)1
通讯作者: 谢作伟
刊名: J. Am. Chem. Soc.
发表日期: 2014
DOI: 10.1021/ja503489b
卷: 136, 期:21, 页:7599-7602
收录类别: SCI
英文摘要: Zirconium/nickel comediated one-pot three-component cascade cyclization of carboryne, alkene, and 2-bromophenyltrimethylsilylacetylene has been achieved, leading to the formation of a series of C,C,B-substituted carborane-fused tricyclics. On the basis of experimental results, a plausible mechanism is proposed including [2 + 2 + 1] cross-cyclotrimerization followed by intramolecular direct selective cage B-C(sp(2)) coupling. This represents the first example of direct cage B-C(phenyl) coupling via cage B-H activation.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39063
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.香港中文大学
2.中科院上海有机化学研究所

Recommended Citation:
Quan YJ,Qiu ZZ,Xie ZW. Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics[J]. J. Am. Chem. Soc.,2014,136(21):7599-7602.
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