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Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles
Alternative Title通过钯催化的吡咯的分子间不对称烯丙基去芳构化高区域选择性以及对映选择性地合成多取代2H-吡咯
Zhuo CX(卓春祥); Zhou Y(周勇); You SL(游书力)
2014
Source PublicationJ. Am. Chem. Soc.
Volume136Issue:18Pages:6590-6593
AbstractA highly efficient synthesis of chiral polysubstituted 2H-pyrrole derivatives via a Pd-catalyzed intermolecular asymmetric allylic dearomatization reaction of pyrroles is presented. With the commercially available palladium precursor and chiral ligand, the polysubstituted 2H-pyrrole products containing a chiral quaternary carbon center were obtained with up to 97% ee and >95/5 regioselectivity.
Subject Area金属有机化学
DOI10.1021/ja5028138
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Indexed BySCI
Language英语
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Cited Times:45[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39059
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhuo CX,Zhou Y,You SL. Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles[J]. J. Am. Chem. Soc.,2014,136(18):6590-6593.
APA 卓春祥,周勇,&游书力.(2014).Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles.J. Am. Chem. Soc.,136(18),6590-6593.
MLA 卓春祥,et al."Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles".J. Am. Chem. Soc. 136.18(2014):6590-6593.
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