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Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization
Alternative Titlebeta-羰基亚胺衍生的金属配合物的合成, 表征及其在苯乙烯聚合催化行为的研究
Xu CJ(许崇杰)1; Chen Z(陈州)1; Shen Q(沈琪)1; Sun XL(孙秀丽)1; Tang Y(唐勇)1
2014
Source PublicationJ. Organomet. Chem.
Volume761Pages:142-146
AbstractThe titanium and zirconium complexes based on thioether substituted beta-carbonylenamine were prepared and characterized. In the presence of MMAO, the titanium complexes showed good activity in syndiospecific styrene polymerization with high syndioselectivity, and performed good thermal stability. Electron withdrawing group on ligands is beneficial to the styrene polymerization. [1,3-diphenyl-3-(2-(isopropylthio)ethylimino)prop-1-en-1-olate](2)ZrCl2(IV) could also polymerize styrene to give syndiotactic polymer, however in low activity and with low syndioselectivity. (C) 2014 Elsevier B.V. All rights reserved.
Subject Area金属有机化学
DOI10.1016/j.jorganchem.2014.02.021
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Indexed BySCI
Language英语
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Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39057
Collection金属有机化学国家重点实验室
Corresponding AuthorSun XL(孙秀丽)
Affiliation1.苏州大学
2.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Xu CJ,Chen Z,Shen Q,et al. Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization[J]. J. Organomet. Chem.,2014,761:142-146.
APA 许崇杰,陈州,沈琪,孙秀丽,&唐勇.(2014).Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization.J. Organomet. Chem.,761,142-146.
MLA 许崇杰,et al."Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization".J. Organomet. Chem. 761(2014):142-146.
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