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学科主题: 金属有机化学
题名: Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization
其他题名: beta-羰基亚胺衍生的金属配合物的合成, 表征及其在苯乙烯聚合催化行为的研究
作者: Xu CJ(许崇杰)1; Chen Z(陈州)1; Shen Q(沈琪)1; Sun XL(孙秀丽)1; Tang Y(唐勇)1
通讯作者: 孙秀丽
刊名: J. Organomet. Chem.
发表日期: 2014
DOI: 10.1016/j.jorganchem.2014.02.021
卷: 761, 页:142-146
收录类别: SCI
英文摘要: The titanium and zirconium complexes based on thioether substituted beta-carbonylenamine were prepared and characterized. In the presence of MMAO, the titanium complexes showed good activity in syndiospecific styrene polymerization with high syndioselectivity, and performed good thermal stability. Electron withdrawing group on ligands is beneficial to the styrene polymerization. [1,3-diphenyl-3-(2-(isopropylthio)ethylimino)prop-1-en-1-olate](2)ZrCl2(IV) could also polymerize styrene to give syndiotactic polymer, however in low activity and with low syndioselectivity. (C) 2014 Elsevier B.V. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39057
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.苏州大学
2.中科院上海有机化学研究所

Recommended Citation:
Xu CJ,Chen Z,Shen Q,et al. Synthesis, characterization, and catalytic behaviors of beta-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization[J]. J. Organomet. Chem.,2014,761:142-146.
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