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学科主题: 金属有机化学
题名: Access to 2(')',3 '-dihydro-1 ' H-spiro[indoline-3,4 '-pyridin]-2-ones via amino acid derived phosphine-catalyzed asymmetric [4+2] annulation with easily available oxindole-derived alpha,beta-unsaturated imines
其他题名: 氨基酸衍生的手性膦催化的靛红亚胺的[4+2]环加成反应
作者: Zhang XN(张肖楠); Dong X(董翔); Wei Y(魏音); Shi M(施敏)
通讯作者: 魏音 ; 施敏
刊名: Tetrahedron
发表日期: 2014
DOI: 10.1016/j.tet.2014.02.052
卷: 70, 期:17, 页:2838-2846
收录类别: SCI
英文摘要: The phosphine-catalyzed asymmetric [4+2] annulation of vinyl ketones with more easily available oxindole-derived alpha,beta-unsaturated imines has been further developed in the presence of an easily available multifunctional thiourea-phosphine catalyst derived from natural amino acid, providing the enantioselective synthesis of 2',3'-dihydro-1'H-spiro[indoline-3,4'-pyridin]-2-ones in good yields and moderate de values with higher enantioselectivities under mild conditions. (C) 2014 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39053
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhang XN,Dong X,Wei Y,et al. Access to 2(')',3 '-dihydro-1 ' H-spiro[indoline-3,4 '-pyridin]-2-ones via amino acid derived phosphine-catalyzed asymmetric [4+2] annulation with easily available oxindole-derived alpha,beta-unsaturated imines[J]. Tetrahedron,2014,70(17):2838-2846.
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