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Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation
Alternative Title通过钯(0)催化的分子内直接C-H键芳基化对映选择性地构建平面手性二茂铁
Gao DW(高得伟); Yin Q(殷勤); Gu Q(顾庆); You SL(游书力)
2014
Source PublicationJ. Am. Chem. Soc.
Volume136Issue:13Pages:4841-4844
AbstractA highly efficient synthesis of planar chiral ferrocenes by enantioselective Pd(0)-catalyzed direct C-H arylation from readily available starting materials under mild reaction conditions was developed (up to 99% yield, 99% ee). The products can be easily transformed to the highly efficient planar ferrocene ligands, which have demonstrated high efficiency in Pd-catalyzed asymmetric allylic alkylation and amination reactions.
Subject Area金属有机化学
DOI10.1021/ja500444v
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Indexed BySCI
Language英语
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Cited Times:96[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39052
Collection金属有机化学国家重点实验室
Corresponding AuthorGu Q(顾庆); You SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Gao DW,Yin Q,Gu Q,et al. Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation[J]. J. Am. Chem. Soc.,2014,136(13):4841-4844.
APA 高得伟,殷勤,顾庆,&游书力.(2014).Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation.J. Am. Chem. Soc.,136(13),4841-4844.
MLA 高得伟,et al."Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation".J. Am. Chem. Soc. 136.13(2014):4841-4844.
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