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学科主题: 金属有机化学
题名: Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation
其他题名: 通过钯(0)催化的分子内直接C-H键芳基化对映选择性地构建平面手性二茂铁
作者: Gao DW(高得伟); Yin Q(殷勤); Gu Q(顾庆); You SL(游书力)
通讯作者: 顾庆 ; 游书力
刊名: J. Am. Chem. Soc.
发表日期: 2014
DOI: 10.1021/ja500444v
卷: 136, 期:13, 页:4841-4844
收录类别: SCI
英文摘要: A highly efficient synthesis of planar chiral ferrocenes by enantioselective Pd(0)-catalyzed direct C-H arylation from readily available starting materials under mild reaction conditions was developed (up to 99% yield, 99% ee). The products can be easily transformed to the highly efficient planar ferrocene ligands, which have demonstrated high efficiency in Pd-catalyzed asymmetric allylic alkylation and amination reactions.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39052
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Gao DW,Yin Q,Gu Q,et al. Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation[J]. J. Am. Chem. Soc.,2014,136(13):4841-4844.
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