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学科主题: 金属有机化学
题名: Pd(II)-Catalyzed One-Step Construction of Cycloalkane-Fused Indoles and Its Application in Formal Synthesis of (+/-)-Aspidospermidine
其他题名: 二价钯催化的吲哚并多元环的构建及其在天然产物(±)-Aspidospermidine合成中的应用
作者: Xia GQ(夏国钦); Han XL(韩秀玲); Lu XY(陆熙炎)
通讯作者: 韩秀玲 ; 陆熙炎
刊名: Org. Lett.
发表日期: 2014
DOI: 10.1021/ol500662f
卷: 16, 期:7, 页:2058-2061
收录类别: SCI
英文摘要: A highly efficient, redox-free Pd(II)-catalyzed tandem cyclization reaction initiated by intramolecular amino-palladation of alkynes followed by nucleophilic addition to nitrites is developed. This method provides a versatile approach for the synthesis of six- to eight-membered ring-fused indoles in one step and has also shown advantages in the formal synthesis of (+/-)-aspidospermidine.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39051
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Xia GQ,Han XL,Lu XY. Pd(II)-Catalyzed One-Step Construction of Cycloalkane-Fused Indoles and Its Application in Formal Synthesis of (+/-)-Aspidospermidine[J]. Org. Lett.,2014,16(7):2058-2061.
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