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A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane
Alternative Title钴催化剂催化的利用频哪醇硼烷参与的烯烃硼氢化反应
Zhang L(张雷); Zuo ZQ(左自青); Leng XB(冷雪冰); Huang Z(黄正)
Source PublicationAngew. Chem.-Int. Edit.
AbstractAn extremely efficient cobalt catalyst for the hydroboration of both vinylarenes and aliphatic -olefins with pinacolborane is described, providing the anti-Markovnikov products with excellent regio- and chemoselectivity, broad functional-group tolerance, and high turnover numbers (up to 19800). The alkene hydroboration route is further extended to a two-step, one-pot hydroboration and cross-coupling of alkylboronates with aryl chlorides.
Subject Area金属有机化学
Indexed BySCI
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Cited Times:130[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorHuang Z(黄正)
Recommended Citation
GB/T 7714
Zhang L,Zuo ZQ,Leng XB,et al. A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane[J]. Angew. Chem.-Int. Edit.,2014,53(10):2696-2700.
APA 张雷,左自青,冷雪冰,&黄正.(2014).A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane.Angew. Chem.-Int. Edit.,53(10),2696-2700.
MLA 张雷,et al."A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane".Angew. Chem.-Int. Edit. 53.10(2014):2696-2700.
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