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学科主题: 金属有机化学
题名: A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane
其他题名: 钴催化剂催化的利用频哪醇硼烷参与的烯烃硼氢化反应
作者: Zhang L(张雷); Zuo ZQ(左自青); Leng XB(冷雪冰); Huang Z(黄正)
通讯作者: 黄正
刊名: Angew. Chem.-Int. Edit.
发表日期: 2014
DOI: 10.1002/anie.201310096
卷: 53, 期:10, 页:2696-2700
收录类别: SCI
英文摘要: An extremely efficient cobalt catalyst for the hydroboration of both vinylarenes and aliphatic -olefins with pinacolborane is described, providing the anti-Markovnikov products with excellent regio- and chemoselectivity, broad functional-group tolerance, and high turnover numbers (up to 19800). The alkene hydroboration route is further extended to a two-step, one-pot hydroboration and cross-coupling of alkylboronates with aryl chlorides.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39049
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Zhang L,Zuo ZQ,Leng XB,et al. A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane[J]. Angew. Chem.-Int. Edit.,2014,53(10):2696-2700.
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