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Asymmetric Chlorination/Ring Expansion for the Synthesis of alpha-Quaternary Cycloalkanones
Alternative Title通过不对称氯化/扩环合成α-季碳环烷酮
Yin Q(殷勤); You SL(游书力)
2014
Source PublicationOrg. Lett.
Volume16Issue:6Pages:1810-1813
AbstractA highly enantioselective chlorination/ring expansion cascade for the construction of cycloalkanones with an all-carbon quaternary center was realized (up to 97% ee). Oxa-cyclobutanol substrates were employed for the first time in the ring expansion reactions, affording the functionalized dihydrofuranones in excellent enantioselectivity.
Subject Area金属有机化学
DOI10.1021/ol5005565
URL查看原文
Indexed BySCI
Language英语
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Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39048
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yin Q,You SL. Asymmetric Chlorination/Ring Expansion for the Synthesis of alpha-Quaternary Cycloalkanones[J]. Org. Lett.,2014,16(6):1810-1813.
APA 殷勤,&游书力.(2014).Asymmetric Chlorination/Ring Expansion for the Synthesis of alpha-Quaternary Cycloalkanones.Org. Lett.,16(6),1810-1813.
MLA 殷勤,et al."Asymmetric Chlorination/Ring Expansion for the Synthesis of alpha-Quaternary Cycloalkanones".Org. Lett. 16.6(2014):1810-1813.
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