| Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes | |
| Alternative Title | 通过钯/铜共催化的2-烯丙基-3-碘代吲哚和末端炔烃的交叉偶联/异构化反应有效合成咔唑的方法 |
| Zhu C(朱灿)1; Ma SM(麻生明)1 | |
| 2014 | |
| Source Publication | Org. Lett.
 |
| Volume | 16Issue:6Pages:1542-1545 |
| Abstract | The Pd/Cu-cocatalyzed one-pot reaction of 2-allyl-3-iodo-1-tosyl-1H-indoles and terminal alkynes afforded carbazoles highly efficiently via sequential carbon carbon coupling, isomerization, cyclization, and aromatization forming a benzene ring. Both Pd and Cu are responsible for the coupling step, while K2CO3 was observed to be critical for the subsequent cyclization. |
| Subject Area | 金属有机化学 |
| DOI | 10.1021/ol500119r |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39047 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Ma SM(麻生明) |
| Affiliation | 1.中科院上海有机化学研究所 2.华东师范大学 |
| Recommended Citation GB/T 7714 | Zhu C,Ma SM. Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes[J]. Org. Lett.,2014,16(6):1542-1545. |
| APA | 朱灿,&麻生明.(2014).Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes.Org. Lett.,16(6),1542-1545. |
| MLA | 朱灿,et al."Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes".Org. Lett. 16.6(2014):1542-1545. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2014149.pdf（568KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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