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学科主题: 金属有机化学
题名: Pyridine-NHC: Effective Ligands in Pd-Catalyzed Cyclopropanation of Esters with Substituted Allyl Carbonates
其他题名: 吡啶-氮杂环卡宾: 用于钯催化酯和单取代烯丙基碳酸酯环丙烷化反应的高效配体
作者: Huang JQ(黄建强); Ding CH(丁昌华); Hou XL(侯雪龙)
通讯作者: 侯雪龙
刊名: J. Org. Chem.
发表日期: 2014
DOI: 10.1021/jo5018712
卷: 79, 期:24, 页:12010-12017
收录类别: SCI
英文摘要: By consideration of the mechanism of Pdcatalyzed cyclopropanation and allylation, NHC-pyridine compounds were adopted as the ligand in Pd-catalyzed cyclopropanation of esters and monosubstituted allylic reagents. The corresponding cyclopropanes were afforded as major products in moderate to good yields with high cyclopropane/allylation selectivity.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39043
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Huang JQ,Ding CH,Hou XL. Pyridine-NHC: Effective Ligands in Pd-Catalyzed Cyclopropanation of Esters with Substituted Allyl Carbonates[J]. J. Org. Chem.,2014,79(24):12010-12017.
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